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4-[2-(2,2-Dimethyl-4,6-dioxo-1,3-dioxan-5-ylidene)hydrazin-1-yl] benzo-nitrile
In the title compound, C 13H 11N 3O 4, the dioxane ring adopts an envelope conformation with the C atom bonded to the dimethyl group in the flap position [deviation = 0.613 (1) Å]. The nitrile group and the attached benzene ... -
Bis(4-methoxybenzoato)-κ2O,O′;κO- bis(nicotinamide-κN1)zinc(II)
The asymmetric unit of the title complex, [Zn(C8H 7O3)2(C6H6N 2O)2], contains three crystallographically independent molecules with similar configurations. The ZnII cation is coordinated by two N atoms of two nicotinamide ... -
Bis(isonicotinamide-κN1)bis(4-methylbenzoato-κO) copper(II) dihydrate
In the centrosymmetric title compound, [Cu(C8H7O 2)2(C6H6N2O) 2]·2H2O, the CuII ion is located on a crystallographic inversion center. The asymmetric unit is completed by one 4-methylbenzoate anion, one isonicotinamide ... -
Boric acid complexes with organic biomolecules: Mono-chelate complexes with salicylic and glucuronic acids
Two mono-chelate borate complexes, lithium mono-salicylatoborate and sodium mono-glucuronatoborate, are reported for the first time. The complexes were isolated from aqueous solutions and characterized by FTIR (Fourier ... -
A comparative examination of mono- and bis-chelate salicylatoborate complexes and the crystal structure of layered magnesium bis-salicylatoborate
Complexes of boric acid with sodium- and magnesium-salicylates were prepared and analyzed to examine the structural consequences resulting from the coordination of the salicylate ligand in mono- and bis-chelate modes. The ... -
Diaquabis(2-bromobenzoato-κO)bis(N,N diethylnicotinamide- κN1)cobalt(II)
In the mononuclear title compound, [Co(C7H4BrO 2)2(C10H14N2O) 2(H2O)2], the CoII ion is located on a crystallographic inversion center. The asymmetric unit is completed by one 2-bromobenzoate anion, one diethylnicotinamide ... -
Ethyl 2-[(2-hydroxybenzylidene)amino]-6-methyl-4,5,6,7-tetrahydrothieno[2, 3-c]pyridine-3-carboxylate
The title compound, C18H20N2O3S, exists as the phenol–imine form in the crystal and there are bifurcated intramolecular O—H…(N/O) hydrogen bonds present. The conformation about the C N bond is anti (1E); the C N imine bond ... -
Tetraaquabis(orotato-O)cobalt(II) dihydrate
In the title CoII complex, [Co(C5H3N 2O4)2(H2O)4]·2H2O, the CoII ion is located on an inversion center and is coordinated by two orotate (2,6-dioxo-1,2,3,6-tetrahydropyrimidine-4-carboxylate) anions and four water mol-ecules ...