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Chemoselective Carbenoid Reactions of Furan/Thiophene/Pyrrole Ring Containing Carbonyl and Conjugated Carbonyl at Their 2-Positions
Seyma Gungor, Fusun; Merey, Gokce; Anac, Olcay (Wiley-V C H Verlag Gmbh, 2020)Several furyl/thiophenyl/N-methylpyrrolyl cores having aldehyde/ketone/ene-biscarbonyl/diene-biscarbonyl functions at their 2-positions were reacted with diazocarbonyl compounds in the presence of metal catalysts. Between ... -
CuCl/AgSbF6 and Rh-2(OAc)(4) Comparison for the Synthesis of N-O Tethered Three and Five Membered Rings via Diazo Chemistry
Merey, Gokce; Kubilay, H. Nur; Anac, Olcay (Chemical Soc Japan, 2021)Diazocarbonyl compounds are versatile precursors of carbenes leading to various structures by using several metal catalysts, especially copper and rhodium salts. In this study, eight different diazocarbonyls having N-O ...