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Hydrogen storage properties of mono-and bidentate MOF structured orotate complexes

Date

2014

Author

Öztürk, Zeynel
Köse, Dursun Ali
Asan, Abdurrahman
Öztürk, Banu
Andaç, Ömer
Özkan, Göksel

Metadata

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Citation

Öztürk, Z., Köse, D. A., Asan, A., Öztürk, B., Andaç, O., Özkan, G. (2014). Hydrogen storage properties of mono-and bidentate MOF structured orotate complexes. Journal of Materials Research, 29(2), 215-220.

Abstract

One of the barriers for wide usage of hydrogen energy system is efficient storage. To store more hydrogen efficiently, physisorption is a choice among the others with high storage performance, reversibility, and lifecycles. Metal organic framework (MOF) structured organometallic orotate-Co(II) complexes could serve as sorbents which store hydrogen by physisorption. In this work, mono-and bidentate MOF structured orotate-Co(II) complexes are synthesized, characterized, and then investigated for hydrogen storage experimentally and theoretically. It is found that these compounds could store hydrogen. Especially, the monodentate complex could uptake hydrogen better than the other. Storage performances for mono-and bidentate complexes were 0.80 and 1.15 wt% at 77 K and approximately 80 bars experimentally, 1.03 and 1.16 wt% theoretically for the same conditions. © 2013 Materials Research Society.

Source

Journal of Materials Research

Volume

29

Issue

2

URI

https://doi.org/10.1557/jmr.2013.357
https://hdl.handle.net/11491/1021

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  • Scopus İndeksli Yayınlar Koleksiyonu
  • WoS İndeksli Yayınlar Koleksiyonu



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