dc.contributor.author | Köse, Dursun Ali | |
dc.contributor.author | Akkurt, Fatih | |
dc.contributor.author | Şahin, Onur | |
dc.contributor.author | Büyükgüngör, Orhan | |
dc.date.accessioned | 2019-05-10T09:38:49Z | |
dc.date.available | 2019-05-10T09:38:49Z | |
dc.date.issued | 2014 | |
dc.identifier.citation | Köse, D. A., Akkurt, F., Şahin, O., Büyükgüngör, O. (2014). Synthesis and Structural Characterization of a Binuclear Mixed‐Ligand (Salicylate and N, N‐diethylnicotinamide) Nickel (II) Complex, Its Magnetic Properties.[Ni2 (µ‐Sal) 4 (Dena) 2] H2O. Journal of the Chinese Chemical Society, 61(12), 1326-1332. | en_US |
dc.identifier.issn | 0009-4536 | |
dc.identifier.uri | https://doi.org/10.1002/jccs.201400292 | |
dc.identifier.uri | https://hdl.handle.net/11491/494 | |
dc.description.abstract | The title complex of [Ni2(?-Sal)4(Dena)2]H2O, [(?-tetrakissalicylato-?-O,O)(bis-N,N-diethylnicotinamide-?-N)(binickel(II))]hydrate, C48H52Ni2N4O16, has been synthesized and explained as structure using some elemental analyses. FT-IR spectra, UV-Vis reflectance, magnetic measurements, thermal analysis and x-ray diffraction methods. The results showed that the unit cell of complex includes two molecules NiII cation, four molecules salicylates as bridge and two molecules N,N-diethylnicotinamide ligands, also there is one molecule hydrated aqua. The compound crystallizes in the monoclinic space group P21/c with the following unit-cell parameters: a = 13.6776(6) A?, b = 10.5238(3) A?, c = 21.8165(9), ? = 90.00°, ? = 126.546(3)°, ? = 90.00° and Z = 2. The compound [Ni2(?-Sal)4(Dena)2]H2O is a typical paddle-wheel complex structure. Two NiII ions are bridged by four salicylate ligands (O2, O2i, O3, O3i, O5, O5i, O6 and O6i) using a ?-COO- coordination mode [symmetry code: (i) 1-x, 1-y, 1-z]. Each NiII also coordinates to one nitrogen atom (N1 and N1i) from one N,N-diethylnicotinamide ligand molecule in the axial position. The complex has strong paramagnetic properties. © 2014 The Chemical Society & Wiley-VCH Verlag GmbH & Co. KGaA. | en_US |
dc.language.iso | eng | |
dc.publisher | Chinese Chemical Society Taiwan | en_US |
dc.relation.isversionof | 10.1002/jccs.201400292 | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Binuclear Carboxylate Complex | en_US |
dc.subject | Binuclear Ni(II) Complex | en_US |
dc.subject | Bridge Salicylate | en_US |
dc.subject | Paddlewheel Structure | en_US |
dc.subject | Strong Paramagnetic | en_US |
dc.title | Synthesis and structural characterization of a binuclear mixed-ligand (Salicylate and N,N-diethylnicotinamide) nickel(II) complex, its magnetic properties. [Ni2(µ‐Sal)4(Dena)2]H2O | en_US |
dc.type | article | en_US |
dc.relation.journal | Journal of the Chinese Chemical Society | en_US |
dc.department | Hitit Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü | en_US |
dc.authorid | 0000-0003-4767-6799 | en_US |
dc.identifier.volume | 61 | en_US |
dc.identifier.issue | 12 | en_US |
dc.identifier.startpage | 1326 | en_US |
dc.identifier.endpage | 1332 | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |