Advanced Search

Show simple item record

dc.contributor.authorKöse, Dursun Ali
dc.contributor.authorAkkurt, Fatih
dc.contributor.authorŞahin, Onur
dc.contributor.authorBüyükgüngör, Orhan
dc.identifier.citationKöse, D. A., Akkurt, F., Şahin, O., Büyükgüngör, O. (2014). Synthesis and Structural Characterization of a Binuclear Mixed‐Ligand (Salicylate and N, N‐diethylnicotinamide) Nickel (II) Complex, Its Magnetic Properties.[Ni2 (µ‐Sal) 4 (Dena) 2] H2O. Journal of the Chinese Chemical Society, 61(12), 1326-1332.en_US
dc.description.abstractThe title complex of [Ni2(?-Sal)4(Dena)2]H2O, [(?-tetrakissalicylato-?-O,O)(bis-N,N-diethylnicotinamide-?-N)(binickel(II))]hydrate, C48H52Ni2N4O16, has been synthesized and explained as structure using some elemental analyses. FT-IR spectra, UV-Vis reflectance, magnetic measurements, thermal analysis and x-ray diffraction methods. The results showed that the unit cell of complex includes two molecules NiII cation, four molecules salicylates as bridge and two molecules N,N-diethylnicotinamide ligands, also there is one molecule hydrated aqua. The compound crystallizes in the monoclinic space group P21/c with the following unit-cell parameters: a = 13.6776(6) A?, b = 10.5238(3) A?, c = 21.8165(9), ? = 90.00°, ? = 126.546(3)°, ? = 90.00° and Z = 2. The compound [Ni2(?-Sal)4(Dena)2]H2O is a typical paddle-wheel complex structure. Two NiII ions are bridged by four salicylate ligands (O2, O2i, O3, O3i, O5, O5i, O6 and O6i) using a ?-COO- coordination mode [symmetry code: (i) 1-x, 1-y, 1-z]. Each NiII also coordinates to one nitrogen atom (N1 and N1i) from one N,N-diethylnicotinamide ligand molecule in the axial position. The complex has strong paramagnetic properties. © 2014 The Chemical Society & Wiley-VCH Verlag GmbH & Co. KGaA.en_US
dc.publisherChinese Chemical Society Taiwanen_US
dc.subjectBinuclear Carboxylate Complexen_US
dc.subjectBinuclear Ni(II) Complexen_US
dc.subjectBridge Salicylateen_US
dc.subjectPaddlewheel Structureen_US
dc.subjectStrong Paramagneticen_US
dc.titleSynthesis and structural characterization of a binuclear mixed-ligand (Salicylate and N,N-diethylnicotinamide) nickel(II) complex, its magnetic properties. [Ni2(µ‐Sal)4(Dena)2]H2Oen_US
dc.relation.journalJournal of the Chinese Chemical Societyen_US
dc.departmentHitit Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümüen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US

Files in this item


There are no files associated with this item.

This item appears in the following Collection(s)

Show simple item record