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dc.contributor.authorKöse, Dursun Ali
dc.contributor.authorYurdakul, Ömer
dc.contributor.authorŞahin, Ozan
dc.contributor.authorÖztürk, Zeynel
dc.date.accessioned2019-05-10T09:39:00Z
dc.date.available2019-05-10T09:39:00Z
dc.date.issued2017
dc.identifier.citationKöse, D. A., Yurdakul, Ö., Şahin, O., & Öztürk, Z. (2017). The new metal complex templated polyoxoborate (s)(POB (s)) structures. Synthesis, structural characterization, and hydrogen storage capacities. Journal of Molecular Structure, 1134, 806-813.en_US
dc.identifier.issn0022-2860
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2017.01.010
dc.identifier.urihttps://hdl.handle.net/11491/579
dc.description.abstractThe polyoxoborate(s) (POB(s)) structures, including a neutral ligand-metal complex compound as a template, were synthesized and the structural characterizations were performed via single crystal X-ray diffraction, FTIR, 11B-NMR, solid state UV–Vis spectroscopy, SEM and elemental analysis methods. Moreover, the stabilization features were determined via TGA/DTA method. In addition, nitrogen and hydrogen adsorption measurements provided the realization to determine the pore size distribution, BET surface area, and hydrogen storage capacities. The molecular formulas of compounds were estimated as [Cu(C12H8N2)2(C2H3O2)][B5O6(OH)4]·2H3BO3·H2O (I) and [Ni(C12H8N2)2(H2O)2]·(B7O9(OH)5)·5H2O (II) and the existence of two different POB(s) structures as pentaborate (B5O6(OH)4) and heptaborate (B7O9(OH)5) within the compounds were observed. At last, it was found that the both structures have micro and mesoporosity with 0.407 and 1.480 m2/g BET surface areas, for the compound I and II, respectively. Moreover, within the same conditions, compound II could uptake 0.19 wt% hydrogen at 77 K and at the relative pressure of 1 while compound II uptakes 0.035 wt% hydrogen. © 2017 Elsevier B.V.en_US
dc.language.isoeng
dc.publisherElsevier B.V.en_US
dc.relation.isversionof10.1016/j.molstruc.2017.01.010en_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCrystal Structureen_US
dc.subjectHeptaborateen_US
dc.subjectHydrogen Storageen_US
dc.subjectMetal-Complex Templated Polyoxoborates (POB(s))en_US
dc.subjectPentaborateen_US
dc.subjectTemplated Polyoxoborates (POB(s))en_US
dc.subjectThermal Analysisen_US
dc.titleThe new metal complex templated polyoxoborate(s) (POB(s)) structures. Synthesis, structural characterization, and hydrogen storage capacitiesen_US
dc.typearticleen_US
dc.relation.journalJournal of Molecular Structureen_US
dc.departmentHitit Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümüen_US
dc.authorid0000-0003-4767-6799en_US
dc.identifier.volume1134en_US
dc.identifier.startpage806en_US
dc.identifier.endpage813en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US


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