dc.contributor.author | Sahin, Zarife Sibel | |
dc.contributor.author | Demir, Mehmet | |
dc.contributor.author | Yildirim, Tugrul | |
dc.contributor.author | Yurdakul, Omer | |
dc.contributor.author | Ali Kose, Dursun | |
dc.date.accessioned | 2021-11-01T15:05:36Z | |
dc.date.available | 2021-11-01T15:05:36Z | |
dc.date.issued | 2021 | |
dc.identifier.issn | 0360-3199 | |
dc.identifier.issn | 1879-3487 | |
dc.identifier.uri | https://doi.org/10.1016/j.ijhydene.2021.06.026 | |
dc.identifier.uri | https://hdl.handle.net/11491/7341 | |
dc.description.abstract | Four novel metal organic framework (MOF) structures containing acesulfame (ace) and 1,10-phenanthroline (phen) ligands of Co2+, Ni2+, Cu2+ and Zn2+ metal cations were synthesized. The crystal structure analysis of three compounds (1, 2, and 3) was also performed. The structural formula for complex 4 is proposed based on spectroscopic and thermal analysis data. It has been determined that structures 1, 2, and 4 are in a distorted octahedral geometry. It has been suggested that the charge balance of the coordination sphere with 2+ is provided by two monoanionic ace ligands located outside the coordination sphere as counter-ion. In structure 3, there are two Cu-II metal cations, two phen ligands coordinated as bidentate to each metal cation and ace ligand that provides monoanionic-monodentate coordination. The Cu2+ cation has distorted bipyramidal geometry. The maximum hydrogen gas adsorption has been found 1.4575 mL/g (0.046 wt%) for the Ni complex. (C) 2021 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved. | en_US |
dc.description.sponsorship | Hitit UniversityHitit University [FEF19004.15.009] | en_US |
dc.description.sponsorship | The authors acknowledge Hitit University Unit of Scientific Research Projects (FEF19004.15.009) and Scientific and Technological Research Application and Research Center, Sinop University, Turkey, for the use of the Bruker D8 QUEST diffractometer. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Pergamon-Elsevier Science Ltd | en_US |
dc.relation.ispartof | International Journal Of Hydrogen Energy | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Acesulfame | en_US |
dc.subject | 1,10-Phenanthroline | en_US |
dc.subject | Coordination compounds | en_US |
dc.subject | Structural properties | en_US |
dc.subject | Thermal decomposition | en_US |
dc.subject | Hydrogen adsorption | en_US |
dc.title | Novel mixed ligand complexes of Co(II), Ni(II), Cu(II), and Zn(II) with 1,10-phenanthroline and acesulfame. Synthesis, structural analysis and hydrogen adsorption study | en_US |
dc.type | article | en_US |
dc.department | [Belirlenecek] | en_US |
dc.authorid | YILDIRIM, Tugrul / 0000-0002-5681-6880 | |
dc.identifier.volume | 46 | en_US |
dc.identifier.issue | 54 | en_US |
dc.identifier.startpage | 27631 | en_US |
dc.identifier.endpage | 27642 | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.department-temp | [Sahin, Zarife Sibel] Sinop Univ, Fac Engn & Architecture, Dept Energy Syst Engn, TR-57000 Sinop, Turkey; [Demir, Mehmet] Sinop Univ, Inst Grad Studies, Dept Interdisciplinary Nucl Energy & Energy Syst, TR-57000 Sinop, Turkey; [Yildirim, Tugrul] Hitit Univ, Tech Sci Vocat Sch, Dept Property Protect & Safety, TR-19100 Corum, Turkey; [Sahin, Zarife Sibel; Yurdakul, Omer; Ali Kose, Dursun] Hitit Univ, Sci & Arts Fac, Dept Chem, TR-19100 Corum, Turkey | en_US |
dc.contributor.institutionauthor | [Belirlenecek] | |
dc.identifier.doi | 10.1016/j.ijhydene.2021.06.026 | |
dc.description.wospublicationid | WOS:000677990300016 | en_US |
dc.description.scopuspublicationid | 2-s2.0-85109452381 | en_US |