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dc.contributor.authorSahin, Zarife Sibel
dc.contributor.authorDemir, Mehmet
dc.contributor.authorYildirim, Tugrul
dc.contributor.authorYurdakul, Omer
dc.contributor.authorAli Kose, Dursun
dc.date.accessioned2021-11-01T15:05:36Z
dc.date.available2021-11-01T15:05:36Z
dc.date.issued2021
dc.identifier.issn0360-3199
dc.identifier.issn1879-3487
dc.identifier.urihttps://doi.org/10.1016/j.ijhydene.2021.06.026
dc.identifier.urihttps://hdl.handle.net/11491/7341
dc.description.abstractFour novel metal organic framework (MOF) structures containing acesulfame (ace) and 1,10-phenanthroline (phen) ligands of Co2+, Ni2+, Cu2+ and Zn2+ metal cations were synthesized. The crystal structure analysis of three compounds (1, 2, and 3) was also performed. The structural formula for complex 4 is proposed based on spectroscopic and thermal analysis data. It has been determined that structures 1, 2, and 4 are in a distorted octahedral geometry. It has been suggested that the charge balance of the coordination sphere with 2+ is provided by two monoanionic ace ligands located outside the coordination sphere as counter-ion. In structure 3, there are two Cu-II metal cations, two phen ligands coordinated as bidentate to each metal cation and ace ligand that provides monoanionic-monodentate coordination. The Cu2+ cation has distorted bipyramidal geometry. The maximum hydrogen gas adsorption has been found 1.4575 mL/g (0.046 wt%) for the Ni complex. (C) 2021 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.en_US
dc.description.sponsorshipHitit UniversityHitit University [FEF19004.15.009]en_US
dc.description.sponsorshipThe authors acknowledge Hitit University Unit of Scientific Research Projects (FEF19004.15.009) and Scientific and Technological Research Application and Research Center, Sinop University, Turkey, for the use of the Bruker D8 QUEST diffractometer.en_US
dc.language.isoengen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofInternational Journal Of Hydrogen Energyen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAcesulfameen_US
dc.subject1,10-Phenanthrolineen_US
dc.subjectCoordination compoundsen_US
dc.subjectStructural propertiesen_US
dc.subjectThermal decompositionen_US
dc.subjectHydrogen adsorptionen_US
dc.titleNovel mixed ligand complexes of Co(II), Ni(II), Cu(II), and Zn(II) with 1,10-phenanthroline and acesulfame. Synthesis, structural analysis and hydrogen adsorption studyen_US
dc.typearticleen_US
dc.department[Belirlenecek]en_US
dc.authoridYILDIRIM, Tugrul / 0000-0002-5681-6880
dc.identifier.volume46en_US
dc.identifier.issue54en_US
dc.identifier.startpage27631en_US
dc.identifier.endpage27642en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.department-temp[Sahin, Zarife Sibel] Sinop Univ, Fac Engn & Architecture, Dept Energy Syst Engn, TR-57000 Sinop, Turkey; [Demir, Mehmet] Sinop Univ, Inst Grad Studies, Dept Interdisciplinary Nucl Energy & Energy Syst, TR-57000 Sinop, Turkey; [Yildirim, Tugrul] Hitit Univ, Tech Sci Vocat Sch, Dept Property Protect & Safety, TR-19100 Corum, Turkey; [Sahin, Zarife Sibel; Yurdakul, Omer; Ali Kose, Dursun] Hitit Univ, Sci & Arts Fac, Dept Chem, TR-19100 Corum, Turkeyen_US
dc.contributor.institutionauthor[Belirlenecek]
dc.identifier.doi10.1016/j.ijhydene.2021.06.026
dc.description.wospublicationidWOS:000677990300016en_US
dc.description.scopuspublicationid2-s2.0-85109452381en_US


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