dc.contributor.author | Bilen, Murat | |
dc.contributor.author | Gürü, Metin | |
dc.contributor.author | Çakanyıldırım, Çetin | |
dc.date.accessioned | 2019-05-10T09:39:42Z | |
dc.date.available | 2019-05-10T09:39:42Z | |
dc.date.issued | 2013 | |
dc.identifier.citation | Bilen, M., Gürü, M., Çakanyıldırım, Ç. (2013). Role of NaCl in NaBH4 production and its hydrolysis. Energy Conversion and Management, 72, 134-140. | en_US |
dc.identifier.issn | 0196-8904 | |
dc.identifier.uri | https://doi.org/10.1016/j.enconman.2012.08.031 | |
dc.identifier.uri | https://hdl.handle.net/11491/755 | |
dc.description.abstract | This study explains completely feasible route to synthesize NaBH 4 by means of mechano-chemical reaction, in which NaCl, B 2O3 and MgH2 were utilized. Optimum reaction conditions were investigated by different values of reactant ratio and duration to reach 95% NaBH4 purity. In addition, commercial NaBH4 was hydrolyzed with CoI2 supported on activated carbon (AC). Intermediate steps of the studies were traced by means of FT-IR, XRD, SEM and EDX analyses. Activation energy of the catalyst was searched at distinct reaction temperatures and found as 36 kJ/mol. Optimum working time for ball-milling reactor and reactant ratio (MgH2/NaCl) were obtained as 1000 min and 1.0, respectively. © 2013 Elsevier Ltd. All rights reserved. | en_US |
dc.language.iso | eng | |
dc.relation.isversionof | 10.1016/j.enconman.2012.08.031 | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Catalytic Dehydrogenation | en_US |
dc.subject | Hydrogen | en_US |
dc.subject | Hydrolysis | en_US |
dc.subject | NaBH4 | en_US |
dc.title | Role of NaCl in NaBH4 production and its hydrolysis | en_US |
dc.type | article | en_US |
dc.relation.journal | Energy Conversion and Management | en_US |
dc.department | Hitit Üniversitesi, Mühendislik Fakültesi, Kimya Mühendisliği Bölümü | en_US |
dc.identifier.volume | 72 | en_US |
dc.identifier.startpage | 134 | en_US |
dc.identifier.endpage | 140 | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |