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    Mössbauer studies and magnetic properties of cubic CuFe2O4 nanoparticles
    (Springer New York LLC, 2019) Amir, Md.; Güngüneş, Hakan; Slimani, Yassine; Tashkandi, N. A.; El Sayed, H. S.; Aldakheel, F.; Sertkol, Murat; Sözeri, Hüseyin; Manikandan, A.; Ercan, İsmail; Baykal, Abdulhadi
    This study reports the preparation and characterization of nanocrystalline spinel powder of cubic copper ferrite nanoparticles (NPs) which have been fabricated via a cost-effective citrate sol–gel approach. The structural and morphological properties of the nanoparticles are analyzed by X-ray diffraction (XRD), Fourier transform spectroscopy (FT-IR), and scanning electron microscopy (SEM) whereas magnetic properties and Mössbauer analysis were performed using vibrating sample magnetometer (VSM) and Mössbauer spectra, respectively, and were characterized in detail. The empirical aim of this study is to perceive the transition phase of CuFe 2 O 4 as cubic symmetry which was confirmed by SEM images, and a couple of studies reported on the cubic structure of copper ferrite and discussed the magnetic properties. However, the present study gives the detailed information of the formation of cubic structure and magnetic behavior of the CuFe 2 O 4 cubic structure. X-ray diffraction measurements of resulting NPs show that the grain size of the particles is about 42.08 nm while SEM analysis showed that the particles have cubic nanostructured shapes with non-homogeneous sizes in around 80–100 nm. From 57 Fe, Mössbauer parameters consist of one superparamagnetic doublet and superposition of four sextets. VSM result shows the enhanced superparamagnetic nature of the CuFe 2 O 4 NPs. © 2018, Springer Science+Business Media, LLC, part of Springer Nature.
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    Substitution effect of Cr 3+ on hyperfine interactions, magnetic and optical properties of Sr-hexaferrites
    (Elsevier Ltd, 2018) Slimani, Yassine; Baykal, Abdulhadi; Amir, Md.; Tashkandi, N. A.; Güngüneş, Hakan; Güner, Sadık; El Sayed, H. S.; Aldakheel, F.; Saleh, Tawfik A.; Manikandan, A.
    Chromium-substituted strontium nano-hexaferrites, SrCrxFe12-xO19 (0.0?? x???1.0), were produced by the hydrothermal route. The structure, morphology, optical and magnetic properties were studied. Crystal structure, spinel phase and functional groups were verified using X-ray diffraction and Fourier Transform Infrared spectroscopy. The average crystallites size is ranging between 50 and 67?nm. Scanning electron microscopy observations indicated that the multi-grains of the particles are aggleromated and are hexagonal in shape. The isotherm plots obtained from the nitrogen physisorption experiments showed that the mesopore area and the total pore volume decreased progressively with increasing the Cr3+ content. Besides, the band gap energy (Eg) decreases from 1.75 to 1.43?eV. The magnetic hysteresis loops showed that the produced nano-hexaferrites exhibit hard ferromagnetic-like (FM) behavior. Compared to the pristine SrFe12O19 product, the deduced saturation (Ms) and remanent (Mr) magnetizations, the coercivity (Hc) and the magnetocrystalline anisotropy field (Ha) increase for lower Cr3+ content (x???0.4) and then decrease as the Cr3+ content further increases. The squareness ratio Mr/Ms are ranging between 0.5 and 0.6, suggesting the single domain nano-sized particles with uniaxial anisotropy for various synthesized products. Mossbauer analysis was done to determine the quadrupole splitting, the isomer shift, and the hyperfine magnetic field values of all products.