Slimani, YassineGüngüneş, HakanNawaz, MuhammadManikandan, A.El Sayed, H. S.Almessiere, Munirah AbdullahSözeri, HüseyinShirsath, Sagar E.Ercan, İsmailBaykal, Abdulhadi2019-05-102019-05-102018Slimani, Y., Güngüneş, H., Nawaz, M., Manikandan, A., El Sayed, H. S., Almessiere, M. A., Sözeri, H., Shirsath, S. E. [et. al.]. (2018). Magneto-optical and microstructural properties of spinel cubic copper ferrites with Li-Al co-substitution. Ceramics International, 44(12), 14242-14250.0272-8842https://doi.org/10.1016/j.ceramint.2018.05.028https://hdl.handle.net/11491/817Nanospinel Li2xCu1-xAlyFe2-yO4 ferrites with composition x?=?y?=?0.0, 0.2, 0.3 and 0.4, were successfully synthesized via hydrothermal method. The effect of co-substitution (Li and Al) on structural, morphological and magnetic properties of CuFe2O4 nanoparticles were investigated using Powder X-ray Diffraction (XRD), Fourier-Transform Infrared spectroscopy (FT-IR), Scanning Electron Microscopy (SEM), Vibrating Sample Magnetometer (VSM) and Mossbauer spectroscopic techniques. The cation distribution of all composition was calculated. Both XRD and FT-IR analyses confirmed the synthesis of single-phase spinel cubic product for all the substitutions. Mossbauer investigation showed that the Li1+ and Al3+ ions occupied B-sites. Nonetheless, some amounts of Li1+ occupy A-site. The magnetization hysteresis loops M (H), revealed that the final products with x, y?=?0.0, 0.3 and 0.4 exhibit superparamagnetic (SPM) behavior at room temperature, however the composition x, y?=?0.2 displays a ferromagnetic-like (FM) behavior. The saturation magnetization (Ms) reduces with rising the Li and Al contents. Compared to pristine CuFe2O4 spinel, the remanent magnetization (Mr), coercive field (Hc) and the magneto-crystalline anisotropy fields (Ha) improved for products synthesized with x, y?=?0.2 and then decrease for x, y?=?0.3 and 0.4. The squareness ratio Mr/Ms are less than 0.500, which suggest the single domain nanoparticles with uniaxial anisotropy for Li2xCu1–xAlyFe2-yO4 (0.0?? x, y???0.4) nanoparticles. The magneto-crystalline anisotropy constant (Keff) value is improved for Li0.8Cu0.6Al0.2Fe1.8O4 (i.e. x, y?=?0.2) magnetic nanoparticles and then decreased for higher Li and Al contents, due to the replacement of Cu and Fe ions with respectively Li and Al ions.eninfo:eu-repo/semantics/closedAccessCation DistributionHyperfine InteractionMagneto-Optical PropertiesSEMSpinel FerritesArticle4412142421425010.1016/j.ceramint.2018.05.028N/AQ1