The structural and thermal characterization of new Cu-Arginate complex; experimental and simulated hydrogen adsorbstion properties

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dc.authorid0000-0003-4767-6799
dc.contributor.authorŞahin, Zarife Sibel
dc.contributor.authorÖztürk, Zeynel
dc.contributor.authorYurdakul, Ömer
dc.contributor.authorKöse, Dursun Ali
dc.date.accessioned2019-07-04T07:14:58Z
dc.date.available2019-07-04T07:14:58Z
dc.date.issued2016
dc.departmentHitit Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü
dc.descriptionresearch
dc.description.abstractThe copper-arginate complex was synthesized and characterized by using FTIR, TG/DTA-DrTG, UV-Vis spectroscopy and elemental analysis methods. In addition, experimental and theoretical hydrogen storage capabilities were investigated. The unit cell of complex structure included that one mole CuII as centered cation and one mole of free NaI cation and one mole of NaSO4- as coordinated to arginine ligand and two moles of arginate ligands and one mole of aqua ligand as coordinated to NaSO4-. The CuII cation had square-pyramidal coordination sphere and the Na1 metal cation had trigonal coordination scheme. The other sodium metal cation (Na2) was implemented in the released position as counter ion of NaSO4-. It was found that the arginine complex, synthesized in this work have 0.533 m2/g BET surface area and 6.92E-3 wt. % hydrogen storage capacity at 77 K and 1 bar while simulated value was 3.27E-3 wt. % for the same conditions.
dc.identifier.citationŞahin, Z. S., ÖZtürk, Z., Yurdakul, Ö., Köse, D. A. (2016). The structural and thermal characterization of new Cu-Arginate complex; experimental and simulated hydrogen adsorbstion properties. Hittite Journal of Science and Engineering, 3(1) 41-49.
dc.identifier.doi10.17350/HJSE19030000031
dc.identifier.endpage49en_US
dc.identifier.issn2149-2123
dc.identifier.issue1en_US
dc.identifier.startpage41en_US
dc.identifier.urihttps://hdl.handle.net/11491/3547
dc.identifier.volume3en_US
dc.indekslendigikaynakTR-Dizin
dc.language.isoen
dc.publisherHitit University
dc.relation.ispartofHittite Journal of Science and Engineering
dc.relation.publicationcategory[Belirlenecek]
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectHelix Structureen_US
dc.subjectArginate Complexen_US
dc.subjectTransition Metal Complexen_US
dc.subjectThermal Decompositionen_US
dc.subjectElectronic Spectraen_US
dc.subjectCu(II) Complexen_US
dc.subjectX-Ray Diffraction Analysisen_US
dc.titleThe structural and thermal characterization of new Cu-Arginate complex; experimental and simulated hydrogen adsorbstion properties
dc.typeArticle

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