Synthesis and structural characterization of a binuclear mixed-ligand (Salicylate and N,N-diethylnicotinamide) nickel(II) complex, its magnetic properties. [Ni2(µ?Sal)4(Dena)2]H2O

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dc.authorid0000-0003-4767-6799
dc.contributor.authorKöse, Dursun Ali
dc.contributor.authorAkkurt, Fatih
dc.contributor.authorŞahin, Onur
dc.contributor.authorBüyükgüngör, Orhan
dc.date.accessioned2019-05-10T09:38:49Z
dc.date.available2019-05-10T09:38:49Z
dc.date.issued2014
dc.departmentHitit Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü
dc.description.abstractThe title complex of [Ni2(?-Sal)4(Dena)2]H2O, [(?-tetrakissalicylato-?-O,O)(bis-N,N-diethylnicotinamide-?-N)(binickel(II))]hydrate, C48H52Ni2N4O16, has been synthesized and explained as structure using some elemental analyses. FT-IR spectra, UV-Vis reflectance, magnetic measurements, thermal analysis and x-ray diffraction methods. The results showed that the unit cell of complex includes two molecules NiII cation, four molecules salicylates as bridge and two molecules N,N-diethylnicotinamide ligands, also there is one molecule hydrated aqua. The compound crystallizes in the monoclinic space group P21/c with the following unit-cell parameters: a = 13.6776(6) A?, b = 10.5238(3) A?, c = 21.8165(9), ? = 90.00°, ? = 126.546(3)°, ? = 90.00° and Z = 2. The compound [Ni2(?-Sal)4(Dena)2]H2O is a typical paddle-wheel complex structure. Two NiII ions are bridged by four salicylate ligands (O2, O2i, O3, O3i, O5, O5i, O6 and O6i) using a ?-COO- coordination mode [symmetry code: (i) 1-x, 1-y, 1-z]. Each NiII also coordinates to one nitrogen atom (N1 and N1i) from one N,N-diethylnicotinamide ligand molecule in the axial position. The complex has strong paramagnetic properties. © 2014 The Chemical Society & Wiley-VCH Verlag GmbH & Co. KGaA.
dc.identifier.citationKöse, D. A., Akkurt, F., Şahin, O., Büyükgüngör, O. (2014). Synthesis and Structural Characterization of a Binuclear Mixed?Ligand (Salicylate and N, N?diethylnicotinamide) Nickel (II) Complex, Its Magnetic Properties.[Ni2 (µ?Sal) 4 (Dena) 2] H2O. Journal of the Chinese Chemical Society, 61(12), 1326-1332.
dc.identifier.doi10.1002/jccs.201400292
dc.identifier.endpage1332en_US
dc.identifier.issn0009-4536
dc.identifier.issue12en_US
dc.identifier.scopusqualityQ2
dc.identifier.startpage1326en_US
dc.identifier.urihttps://doi.org/10.1002/jccs.201400292
dc.identifier.urihttps://hdl.handle.net/11491/494
dc.identifier.volume61en_US
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherChinese Chemical Society Taiwan
dc.relation.ispartofJournal of the Chinese Chemical Society
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectBinuclear Carboxylate Complexen_US
dc.subjectBinuclear Ni(II) Complexen_US
dc.subjectBridge Salicylateen_US
dc.subjectPaddlewheel Structureen_US
dc.subjectStrong Paramagneticen_US
dc.titleSynthesis and structural characterization of a binuclear mixed-ligand (Salicylate and N,N-diethylnicotinamide) nickel(II) complex, its magnetic properties. [Ni2(µ?Sal)4(Dena)2]H2O
dc.typeArticle

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