Influence of epoxy addition on the thermal, mechanical, and dielectrical properties of polycyanurate films

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dc.authorid0000-0002-3110-0675
dc.authorid0000-0002-0915-2911
dc.contributor.authorOkutan, Merve
dc.contributor.authorSarıboğa, Vedat
dc.contributor.authorYıldırım, Saffettin
dc.contributor.authorDeligöz, Hüseyin
dc.date.accessioned2019-05-10T09:39:13Z
dc.date.available2019-05-10T09:39:13Z
dc.date.issued2018
dc.departmentHitit Üniversitesi, Mühendislik Fakültesi, Kimya Mühendisliği Bölümü
dc.description.abstractIn the study, polycyanurate (PCN)/epoxy resin (ER) blends are prepared to enhance the physical properties of cyanate ester resins. The effects of curing schedule and blend composition on their thermal, mechanical, and dielectrical properties of cured PCN/epoxy blend films are examined. FTIR analysis of the cured blend films exhibits the expected cyanurate and oxazolidinone peaks in all blend compositions except the film thermally treated for 1 h in the presence of 1% phenol. TGA results show that the thermal stability decreases with epoxy content in the blend film. From SEM analyses, it is observed that all films have very dense, smooth, and bubble free surface without phase separation. For the pure PCN, the dielectric constants are found to be 3.54–5.91 in the range of 10?1–107 Hz between 20°C and 200°C. PCN/epoxy blends up to 50% epoxy resin show a good stability of dielectric constant in this frequency band for 200°C, which is close to the dielectric constant of the homopolymerized PCN. Beyond this percentage of epoxy resin, dielectric constants of PCN/epoxy blends greatly increase at low-frequency region (0.1–103 Hz) due to the interfacial polarization governed by Maxwell–Wagner–Sillars effect. POLYM. ENG. SCI., 58:820–829, 2018. © 2017 Society of Plastics Engineers. © 2017 Society of Plastics Engineers
dc.identifier.citationDeniz, M., Sarıboğa, V., Yıldırım, S., & Deligöz, H. (2018). Influence of epoxy addition on the thermal, mechanical, and dielectrical properties of polycyanurate films. Polymer Engineering & Science, 58(6), 820-829.
dc.identifier.doi10.1002/pen.24627
dc.identifier.endpage829en_US
dc.identifier.issn0032-3888
dc.identifier.issue6en_US
dc.identifier.scopusqualityQ2
dc.identifier.startpage820en_US
dc.identifier.urihttps://doi.org/10.1002/pen.24627
dc.identifier.urihttps://hdl.handle.net/11491/639
dc.identifier.volume58en_US
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherJohn Wiley and Sons Inc.
dc.relation.ispartofPolymer Engineering and Science
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subject[Belirlenecek]en_US
dc.titleInfluence of epoxy addition on the thermal, mechanical, and dielectrical properties of polycyanurate films
dc.typeArticle

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