Electrochemical investigation of Zinc(II)-furdap amide complex in DMSO medium

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dc.authorid0000-0002-5807-3494
dc.authorid0000-0002-0275-3941
dc.authorid0000-0002-8016-3082
dc.contributor.authorGökmeşe, Faruk
dc.contributor.authorGökmeşe, Ebru
dc.contributor.authorHamurcu, Fatma
dc.contributor.authorÇelikkan, Hüseyin
dc.contributor.authorAksu, Mehmet Levent
dc.date.accessioned2019-05-13T09:04:50Z
dc.date.available2019-05-13T09:04:50Z
dc.date.issued2009
dc.departmentHitit Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü
dc.description.abstractThe electrochemical behavior of Zinc(II)-furdap amide complex has been investigated by the use of several electrochemical methods in DMSO on platinum electrode. Both the ligand and the complex gave one electron transfer reduction. Although there was no oxidation peak observed corresponding to the reduction of ligand, there was a corresponding oxidation peak appeared for the complex. The number of electrons transferred was calculated as 1 by the use of bulk electrolysis, rotating disc electrodes employing KouteckTimesNewRomanPSMT.0.5 -Levich equation. The reversibility tests revealed that the reaction followed a quasi reversible mechanism. The mechanism was also confirmed by simulation studies. ks and ? values were found to be 1.0×10-7 cm s-1 and 0.4, respectively. The diffusion coefficient (D) was found as 6.93 ×10-5 cm2 s-1 by the use of Cottrell slope obtained from chronoamperometry experiments and ultra micro disc steady state current (iss). © 2009 Bentham Science Publishers Ltd.
dc.identifier.citationGokmese, F., Gokmese, E., Hamurcu, F., Celikkan, H., & Aksu, M. L. (2009). Electrochemical investigation of Zinc (II)-furdap amide complex in DMSO medium. Current Analytical Chemistry, 5(3), 244-248.
dc.identifier.doi10.2174/157341109788680246
dc.identifier.endpage248en_US
dc.identifier.issn1573-4110
dc.identifier.issue3en_US
dc.identifier.scopusqualityQ2
dc.identifier.startpage244en_US
dc.identifier.urihttps://doi.org/10.2174/157341109788680246
dc.identifier.urihttps://hdl.handle.net/11491/1648
dc.identifier.volume5en_US
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.relation.ispartofCurrent Analytical Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectAmide Complexesen_US
dc.subjectElectrochemistryen_US
dc.subjectRotating Disc Electrodeen_US
dc.subjectZinc(II) Complexesen_US
dc.titleElectrochemical investigation of Zinc(II)-furdap amide complex in DMSO medium
dc.typeArticle

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