Synthesis and structures of Fe(II), Zn(II) and Pd(II) complexes with a schiff base derived from methyl 2-amino-6-methyl-4,5,6,7-tetrahydrothieno[2,3-c] pyridine-3-carboxylate and comparison of their optical constants for different solvents and molarities

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dc.authorid0000-0001-7181-9556
dc.contributor.authorTuran, Nevin
dc.contributor.authorBuldurun, Kenan
dc.contributor.authorGündüz, Bayram
dc.contributor.authorÇolak, Naki
dc.date.accessioned2019-05-13T09:08:43Z
dc.date.available2019-05-13T09:08:43Z
dc.date.issued2017
dc.departmentHitit Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü
dc.description.abstractSchiff base derived from condensation of o-vanillin (3-methoxysalicylaldehyde) and methyl 2-amino-6-methyl- 4,5,6,7-tetrahydrothieno[2,3-c]pyridine-3-carboxylate and its metal complexes are synthesized and characterized based on elemental analyses, IR, 1H NMR, 13C NMR, magnetic susceptibility, mass spectra, UV-vis and thermal analysis (TGA). Specifically the spectral measurements display the octahedral structures of Fe(II), Zn(II) complexes and square planar geometry of Pd(II) complex. Here, the effects on optical constants such as absorbance, molar extinction coefficient, mass extinction coefficients, transmittance, absorption band edge and optical band gap of Fe(II), Zn(II) and Pd(II) complexes of the different solvents (dichloromethane (DCM), acetone and ethyl alcohol (EtOH)) and molarities (0.498, 0.249 and 0.124 mM) are investigated by solution technique. Copyright © 2017 by American Scientific Publishers All rights reserved.
dc.identifier.citationTuran, N., Buldurun, K., Gündüz, B., Çolak, N. (2017). Synthesis and structures of Fe (II), Zn (II) and Pd (II) complexes with a schiff base derived from methyl 2-amino-6-methyl-4, 5, 6, 7-tetrahydrothieno [2, 3-c] pyridine-3-carboxylate and comparison of their optical constants for different solvents and molarities. Journal of Nanoelectronics and Optoelectronics, 12(9), 1028-1040.
dc.identifier.doi10.1166/jno.2017.2151
dc.identifier.endpage1040en_US
dc.identifier.issn1555-130X
dc.identifier.issue9en_US
dc.identifier.scopusqualityN/A
dc.identifier.startpage1028en_US
dc.identifier.urihttps://doi.org/10.1166/jno.2017.2151
dc.identifier.urihttps://hdl.handle.net/11491/2040
dc.identifier.volume12en_US
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherAmerican Scientific Publishers
dc.relation.ispartofJournal of Nanoelectronics and Optoelectronics
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectAbsorptionen_US
dc.subjectCarboxylate Liganden_US
dc.subjectElectrical Sensingen_US
dc.subjectOptical Band Gapen_US
dc.subjectPalladiumen_US
dc.subjectStructure Elucidationen_US
dc.titleSynthesis and structures of Fe(II), Zn(II) and Pd(II) complexes with a schiff base derived from methyl 2-amino-6-methyl-4,5,6,7-tetrahydrothieno[2,3-c] pyridine-3-carboxylate and comparison of their optical constants for different solvents and molarities
dc.typeArticle

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