Role of NaCl in NaBH4 production and its hydrolysis
[ X ]
Tarih
2013
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
This study explains completely feasible route to synthesize NaBH 4 by means of mechano-chemical reaction, in which NaCl, B 2O3 and MgH2 were utilized. Optimum reaction conditions were investigated by different values of reactant ratio and duration to reach 95% NaBH4 purity. In addition, commercial NaBH4 was hydrolyzed with CoI2 supported on activated carbon (AC). Intermediate steps of the studies were traced by means of FT-IR, XRD, SEM and EDX analyses. Activation energy of the catalyst was searched at distinct reaction temperatures and found as 36 kJ/mol. Optimum working time for ball-milling reactor and reactant ratio (MgH2/NaCl) were obtained as 1000 min and 1.0, respectively. © 2013 Elsevier Ltd. All rights reserved.
Açıklama
Anahtar Kelimeler
Catalytic Dehydrogenation, Hydrogen, Hydrolysis, NaBH4
Kaynak
Energy Conversion and Management
WoS Q Değeri
N/A
Scopus Q Değeri
Q1
Cilt
72
Sayı
Künye
Bilen, M., Gürü, M., Çakanyıldırım, Ç. (2013). Role of NaCl in NaBH4 production and its hydrolysis. Energy Conversion and Management, 72, 134-140.
