CuCl/AgSbF6 and Rh-2(OAc)(4) Comparison for the Synthesis of N-O Tethered Three and Five Membered Rings via Diazo Chemistry

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dc.contributor.authorMerey, Gokce
dc.contributor.authorKubilay, H. Nur
dc.contributor.authorAnac, Olcay
dc.date.accessioned2021-11-01T15:05:37Z
dc.date.available2021-11-01T15:05:37Z
dc.date.issued2021
dc.department[Belirlenecek]
dc.description.abstractDiazocarbonyl compounds are versatile precursors of carbenes leading to various structures by using several metal catalysts, especially copper and rhodium salts. In this study, eight different diazocarbonyls having N-O moiety were used. The N-O tethered structures were prefened because they may allow some useful transformations of the final products into valuable compounds via N-O cleavage. In the presence of a double bond on the -OR function of the starting diazo compound, CuCl/AgSbF6 catalyst yielded only cyclopropyl fused oxazinane/oxazepane derivatives over cyclopropanation while Rh-2(OAc)(4) catalyst was giving mainly isooxazolidinones via C-H insertion.
dc.description.sponsorshipIstanbul Technical University Scientific Research Project [TDK-2017-40693]en_US
dc.description.sponsorshipThis work was supported by Istanbul Technical University Scientific Research Project (No: TDK-2017-40693).en_US
dc.identifier.doi10.1246/cl.200863
dc.identifier.endpage671en_US
dc.identifier.issn0366-7022
dc.identifier.issn1348-0715
dc.identifier.issue4en_US
dc.identifier.scopus2-s2.0-85104996335
dc.identifier.scopusqualityQ3
dc.identifier.startpage668en_US
dc.identifier.urihttps://doi.org/10.1246/cl.200863
dc.identifier.urihttps://hdl.handle.net/11491/7348
dc.identifier.volume50en_US
dc.identifier.wosWOS:000635555000021
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthor[Belirlenecek]
dc.language.isoen
dc.publisherChemical Soc Japan
dc.relation.ispartofChemistry Letters
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectCarbenoiden_US
dc.subjectDiazoen_US
dc.subjectN-O moietyen_US
dc.titleCuCl/AgSbF6 and Rh-2(OAc)(4) Comparison for the Synthesis of N-O Tethered Three and Five Membered Rings via Diazo Chemistry
dc.typeArticle

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