Nicotinamide-modified poly(HEMA-GMA)-Nic cryogels for removal of pesticides

Yükleniyor...
Küçük Resim

Tarih

2018

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Turkish Chemical Society

Erişim Hakkı

info:eu-repo/semantics/openAccess

Özet

Chlordane is only one of the persistent pesticides used in some countries despite the ban. Removal of chlordane, a severe threat to all living things, was performed using nicotinamide-modified poly (2-hydroxyethyl methacrylate-glycidyl methacrylate), poly(HEMA-GMA)-Nic, polymeric cryogels in this study. Poly(HEMA-GMA) polymeric cryogels were synthesized based on previously reported literature procedures and were subsequently modified by nicotinamide moieties. Removal of chlordane in alcoholic medium has been accomplished exploiting the alcoho-phobic interaction, which was the first indication in our previous study. Structural analysis of poly(HEMA-GMA)-Nic was performed using Fourier transform infrared spectroscopy (FT-IR) and elemental analysis methods. Scanning electron microscopy (SEM) was used to understand the surface morphology of cryogels. Surface area and cavity volume calculations were determined by applying N 2 adsorption method and swelling test. The interaction time and maximum adsorption capacity were identified as 5 minutes and 64.61 mg chlordane/g cryogel for 300 mg/L chlordane concentration and 108.818 mg chlordane/g cryogel for 800 mg/L chlordane concentration during the adsorption experiments. Cyclohexane, toluene, chloroform, dichloromethane, acetone, and acetonitrile were used as solvents to observe the solvent effect on adsorption of chlordane onto the polymeric material. As expected, the removal of chlordane was performed with the highest adsorption performance in cyclohexane with the lowest dielectric constant. © 2018, Turkish Chemical Society. All rights reserved.

Açıklama

Anahtar Kelimeler

Alcoho-Phobic, Chlordane, Cryogel, Nicotinamide, Pesticide

Kaynak

Journal of the Turkish Chemical Society, Section A: Chemistry

WoS Q Değeri

Scopus Q Değeri

Q3

Cilt

5

Sayı

2

Künye

Köse, K., Arslan Akveran, G., Erol, K., Köse, D. A. (2018). Nicotinamide-modified poly (HEMA-GMA)-Nic cryogels for removal of pesticides. Journal of the Turkish Chemical Society, Section A: Chemistry, 5(2), 941-952.