Novel mixed ligand complexes of Co(II), Ni(II), Cu(II), and Zn(II) with 1,10-phenanthroline and acesulfame. Synthesis, structural analysis and hydrogen adsorption study

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dc.authoridYILDIRIM, Tugrul / 0000-0002-5681-6880
dc.contributor.authorSahin, Zarife Sibel
dc.contributor.authorDemir, Mehmet
dc.contributor.authorYildirim, Tugrul
dc.contributor.authorYurdakul, Omer
dc.contributor.authorAli Kose, Dursun
dc.date.accessioned2021-11-01T15:05:36Z
dc.date.available2021-11-01T15:05:36Z
dc.date.issued2021
dc.department[Belirlenecek]
dc.description.abstractFour novel metal organic framework (MOF) structures containing acesulfame (ace) and 1,10-phenanthroline (phen) ligands of Co2+, Ni2+, Cu2+ and Zn2+ metal cations were synthesized. The crystal structure analysis of three compounds (1, 2, and 3) was also performed. The structural formula for complex 4 is proposed based on spectroscopic and thermal analysis data. It has been determined that structures 1, 2, and 4 are in a distorted octahedral geometry. It has been suggested that the charge balance of the coordination sphere with 2+ is provided by two monoanionic ace ligands located outside the coordination sphere as counter-ion. In structure 3, there are two Cu-II metal cations, two phen ligands coordinated as bidentate to each metal cation and ace ligand that provides monoanionic-monodentate coordination. The Cu2+ cation has distorted bipyramidal geometry. The maximum hydrogen gas adsorption has been found 1.4575 mL/g (0.046 wt%) for the Ni complex. (C) 2021 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
dc.description.sponsorshipHitit UniversityHitit University [FEF19004.15.009]en_US
dc.description.sponsorshipThe authors acknowledge Hitit University Unit of Scientific Research Projects (FEF19004.15.009) and Scientific and Technological Research Application and Research Center, Sinop University, Turkey, for the use of the Bruker D8 QUEST diffractometer.en_US
dc.identifier.doi10.1016/j.ijhydene.2021.06.026
dc.identifier.endpage27642en_US
dc.identifier.issn0360-3199
dc.identifier.issn1879-3487
dc.identifier.issue54en_US
dc.identifier.scopus2-s2.0-85109452381
dc.identifier.scopusqualityQ1
dc.identifier.startpage27631en_US
dc.identifier.urihttps://doi.org/10.1016/j.ijhydene.2021.06.026
dc.identifier.urihttps://hdl.handle.net/11491/7341
dc.identifier.volume46en_US
dc.identifier.wosWOS:000677990300016
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthor[Belirlenecek]
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofInternational Journal Of Hydrogen Energy
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectAcesulfameen_US
dc.subject1,10-Phenanthrolineen_US
dc.subjectCoordination compoundsen_US
dc.subjectStructural propertiesen_US
dc.subjectThermal decompositionen_US
dc.subjectHydrogen adsorptionen_US
dc.titleNovel mixed ligand complexes of Co(II), Ni(II), Cu(II), and Zn(II) with 1,10-phenanthroline and acesulfame. Synthesis, structural analysis and hydrogen adsorption study
dc.typeArticle

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