Direct electrochemical reduction of copper sulfide in molten borax

dc.authoridTimur, Servet rusen / 0000-0002-9795-9941
dc.authoridkartal, levent / 0000-0002-6291-8947
dc.authorwosidkartal, levent / R-6668-2019
dc.authorwosidTimur, Servet rusen / J-2893-2012
dc.contributor.authorKartal, Levent
dc.contributor.authorTimur, Servet
dc.date.accessioned2021-11-01T15:02:02Z
dc.date.available2021-11-01T15:02:02Z
dc.date.issued2019
dc.department[Belirlenecek]
dc.description.abstractIn this study, for the first time, direct copper production from copper sulfide was carried out via direct electrochemical reduction method using inexpensive and stable molten borax electrolyte. The effects of current density (100-800 mA/cm(2)) and electrolysis time (15-90 min) on both the cathodic current efficiency and copper yield were systematically investigated in consideration of possible electrochemical/chemical reactions at 1200 degrees C. The copper production yield reached 98.09% after 90 min of electrolysis at a current density of 600 mA/cm(2). Direct metal production was shown to be possible with 6 kWh/kg energy consumption at a 600 mA/cm(2) current density, at which the highest current efficiency (41%) was obtained. The suggested method can also be applied to metal/alloy production from single- and mixed-metal sulfides coming from primary production and precipitated sulfides, which are produced in the mining and metallurgical industries during treatment of process solutions or wastewaters.
dc.identifier.doi10.1007/s12613-019-1821-x
dc.identifier.endpage998en_US
dc.identifier.issn1674-4799
dc.identifier.issn1869-103X
dc.identifier.issue8en_US
dc.identifier.scopus2-s2.0-85069750508
dc.identifier.scopusqualityQ1
dc.identifier.startpage992en_US
dc.identifier.urihttps://doi.org/10.1007/s12613-019-1821-x
dc.identifier.urihttps://hdl.handle.net/11491/6814
dc.identifier.volume26en_US
dc.identifier.wosWOS:000477642900008
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthor[Belirlenecek]
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofInternational Journal Of Minerals Metallurgy And Materials
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectmolten salt electrolysisen_US
dc.subjectelectro-reductionen_US
dc.subjectcopper extractionen_US
dc.subjectcopper sulfideen_US
dc.subjectboraxen_US
dc.titleDirect electrochemical reduction of copper sulfide in molten borax
dc.typeArticle

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