Electrochemical properties of copper complex of Furdap amide in non-aqueous medium
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Tarih
2011
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
The electrochemical behavior of Cu (II)-Furdap amide complex has been investigated by the use of several electrochemical methods in DMSO on platinum electrode. The number of electrons transferred was calculated by bulk electrolysis and rotating disc electrodes. The reversibility tests were applied to elucidate the reaction mechanism. It was found that the Cu (II)- Furdap complex is reduced with quasi-reversible reaction. The mechanism of the electrode reaction was confirmed by simulation experiments. The standard heterogeneous rate constant (7×10-4 cm s-1), the charge transfer coefficient (0.5), and the diffusion coefficient (1.7×10-6 cm2 s-1) were found by simulation study. © 2011 by ESG.
Açıklama
Anahtar Kelimeler
Amide Complexes, Copper (II) Complexes, Electrochemistry, Rotating Disc Electrode, Simulation Cyclic Voltammetry
Kaynak
International Journal of Electrochemical Science
WoS Q Değeri
N/A
Scopus Q Değeri
Q3
Cilt
6
Sayı
1
Künye
Gökmeşe, E. (2011). Electrochemical properties of copper complex of Furdap amide in non-aqueous medium. Int. J. Electrochem. Sci, 6, 103-112.
