Solvent effects on the electronic and optical properties of Ni(II), Zn(II), and Fe(II) complexes of a Schiff base derived from 5-bromo-2-hydroxybenzaldehyde

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dc.authoridTuran, Nevin / 0000-0001-6740-6812
dc.authoridBULDURUN, Kenan / 0000-0002-2462-7006
dc.contributor.authorBuldurun, Kenan
dc.contributor.authorTanis, Emine
dc.contributor.authorTuran, Nevin
dc.contributor.authorColak, Naki
dc.contributor.authorCankaya, Nevin
dc.date.accessioned2021-11-01T15:06:00Z
dc.date.available2021-11-01T15:06:00Z
dc.date.issued2021
dc.department[Belirlenecek]
dc.description.abstractIn this article, the electronic, optical, and charge transfer properties of a Schiff base ligand prepared using 5-bromo-2-hydroxybenzaldehyde and ethyl 6-acetyl-2-amino-4,5,6,7-tetrahydrothieno[2,3-c]pyridine-3-carboxylate (C19H19BrN2O4S) and its Fe(II) (C19H30BrN2O10SClFe), Ni(II) (C19H28BrN2O9SClNi), and Zn(II) (C19H28BrN2O9SClZn) complexes are described based on different solvents environments and supported by theoretical calculations. Theoretical calculations are carried out using density functional theory (DFT/UB3LYP/LANL2DZ). The optical densities, optical band gaps, and refractive indices of the ligand and its Fe(II), Ni(II), and Zn(II) complexes in different solvent environments are obtained. The reorganization energies are calculated to determine the charge transfer rate of the studied compounds using both experimental and theoretical data. These experimental and theoretical results show that the ligand and its metal complexes can be used for optoelectronic applications and charge transfer materials in organic light-emitting diode applications.
dc.identifier.doi10.1177/1747519821995424
dc.identifier.endpage759en_US
dc.identifier.issn1747-5198
dc.identifier.issn2047-6507
dc.identifier.issue7-8en_US
dc.identifier.scopus2-s2.0-85101712932
dc.identifier.scopusqualityQ3
dc.identifier.startpage753en_US
dc.identifier.urihttps://doi.org/10.1177/1747519821995424
dc.identifier.urihttps://hdl.handle.net/11491/7463
dc.identifier.volume45en_US
dc.identifier.wosWOS:000681454700001
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthor[Belirlenecek]
dc.language.isoen
dc.publisherSage Publications Ltd
dc.relation.ispartofJournal Of Chemical Research
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectcharge transfer propertiesen_US
dc.subjectmetal complexesen_US
dc.subjectnonlinear optical propertiesen_US
dc.subjectoptical parametersen_US
dc.subjectSchiff baseen_US
dc.titleSolvent effects on the electronic and optical properties of Ni(II), Zn(II), and Fe(II) complexes of a Schiff base derived from 5-bromo-2-hydroxybenzaldehyde
dc.typeArticle

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