Organic biomolecules bind to phosphate through borate linkages in aqueous solutions

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dc.authorid0000-0003-4767-6799
dc.contributor.authorAydoğmuş, Nazik
dc.contributor.authorKöse, Dursun Ali
dc.contributor.authorBeckett, Micheal Andrew
dc.contributor.authorZümreoğlu Karan, Birgül
dc.date.accessioned2019-05-13T09:02:50Z
dc.date.available2019-05-13T09:02:50Z
dc.date.issued2014
dc.departmentHitit Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü
dc.description.abstractSolutions of salicyclic, ascorbic, and citric acids were reacted with boric acid, followed by NaH2PO4. The products, triphosphateborate ester of salicylic acid (1), orthosphateborate ester of ascorbic acid (2), triphosphateborate ester of ascorbic acid (3), and orthosphateborate ester of citric acid (4), were ash precipitated with cold acetone and characterised by microanalysis, thermal analysis, FT-IR, Raman, 11B NMR, 31P MAS NMR, and mass spectroscopic techniques. Analytical results indicated the presence of-C-O-B-O-P-linkages with the attached phosphate groups varying between orthophosphate and triphosphate, depending on the starting material. The biomolecules studied in this work may serve as models in the B-P-organic system and the results would provide a possible contribution to boronprebiotic chemistry.© TÜBİTAK.
dc.identifier.citationAydoğmuş, N., Köse, D. A., Beckett, M. A., Zümreoğlu Karan, B. (2014). Organic biomolecules bind to phosphate through borate linkages in aqueous solutions. Turkish Journal of Chemistry, 38(4), 617-628.
dc.identifier.doi10.3906/kim-1309-55
dc.identifier.endpage628en_US
dc.identifier.issn1300-0527
dc.identifier.issue4en_US
dc.identifier.scopusqualityQ3
dc.identifier.startpage617en_US
dc.identifier.urihttps://doi.org/10.3906/kim-1309-55
dc.identifier.urihttps://hdl.handle.net/11491/1344
dc.identifier.volume38en_US
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTÜBİTAK
dc.relation.ispartofTurkish Journal of Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectBorate Complexen_US
dc.subjectBoric Aciden_US
dc.subjectPhosphate Esteren_US
dc.titleOrganic biomolecules bind to phosphate through borate linkages in aqueous solutions
dc.typeArticle

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