Water-soluble polymeric particle embedded cryogels: Synthesis, characterisation and adsorption of haemoglobin

[ X ]

Tarih

2021

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Walter De Gruyter Gmbh

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

Making cryogels, which are among today's accepted adsorbents, more functional with different methods, has been one of the subjects spent overtime. In this study, water-soluble poly(maleic anhydride-alt-acrylic acid) polymer embedded in poly(2-hydroxyethyl methacrylate) cryogels. Copper ionswere then immobilised to this structure, and this polymer was used for adsorption of haemoglobin from aqueous systems. Adsorption interaction was carried out on an electrostatic basis, and approximately 448.62 mg haemoglobin/g polymer adsorption capacity value was obtained. Itwas found that the same material hasmanaged to maintain its adsorption ability by 90.3% even after the use of it five times in the adsorption/desorption cycle. The adsorption interaction was determined to be appropriate for the Langmuir model by isotherm studies. The change in Gibbs free energy value was calculated as -2.168 kJ/mol.

Açıklama

Anahtar Kelimeler

Adsorption, Copper, Cryogel, Haemoglobin, Particle Embedded

Kaynak

Journal Of Polymer Engineering

WoS Q Değeri

Q4

Scopus Q Değeri

Q3

Cilt

41

Sayı

8

Künye

Erol, K., Bülter, M. B., Köse, D. A., & Can, H. K. (2021). Water-soluble polymeric particle embedded cryogels: Synthesis, characterisation and adsorption of haemoglobin. Journal of Polymer Engineering, 41(8), 671-680.