An effective trimetalic crystalline catalyst for sodium borohydride hydrolysis

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dc.authoridCAKANYILDIRIM, CETIN / 0000-0001-7040-1369
dc.contributor.authorCakanyildirim, Cetin
dc.date.accessioned2021-11-01T15:03:07Z
dc.date.available2021-11-01T15:03:07Z
dc.date.issued2020
dc.department[Belirlenecek]
dc.description.abstractIn this study, synthesis and application of Co0.92-xFe0.08Rux/TiO2 nano catalysts for the hydrolysis reaction of NaBH4 are reported. Several catalysts were synthesized with cobalt, iron and ruthenium salts by wet impregnation technique. Characterization of the catalysts was done by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), X-ray powder diffraction (XRD), transmission electron microscopy (TEM) and hydrolysis tests. Analysis results show that the precursors are strongly adhered on the surface with nono size alloy formation and catalyst can produce 18,800 mL H-2/min.g(cat) with 0.525 M of NaBH4 solution at 20 degrees C. Kinetic investigation reveals that the catalyst works according to zero-order kinetics and the activation energy is 34.5. Durability tests prove that the activation loss of which catalyst is maximum 37% after ten runs.
dc.description.sponsorshipHitit University BAP (Scientific Research Projects) unit [MUH19001.19.001]en_US
dc.description.sponsorshipThis work was supported by the Hitit University BAP (Scientific Research Projects) unit with project number MUH19001.19.001.en_US
dc.identifier.doi10.1080/15567036.2020.1842558
dc.identifier.issn1556-7036
dc.identifier.issn1556-7230
dc.identifier.scopus2-s2.0-85095797199
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1080/15567036.2020.1842558
dc.identifier.urihttps://hdl.handle.net/11491/6978
dc.identifier.wosWOS:000585424500001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthor[Belirlenecek]
dc.language.isoen
dc.publisherTaylor & Francis Inc
dc.relation.ispartofEnergy Sources Part A-Recovery Utilization And Environmental Effects
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectHydrogen generationen_US
dc.subjectsodium borohydrideen_US
dc.subjectsupported catalysten_US
dc.subjecthydrolysisen_US
dc.subjectkineticsen_US
dc.titleAn effective trimetalic crystalline catalyst for sodium borohydride hydrolysis
dc.typeArticle

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