Mn(II) and Co(II) mixed-ligand coordination compounds with acesulfame and 3-aminopyridine: synthesis and structural properties

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dc.authoridÖzer, Demet / 0000-0003-0862-9607
dc.contributor.authorYurdakul, Ömer
dc.contributor.authorKöse, Dursun Ali
dc.contributor.authorŞahin, Onur
dc.contributor.authorÖzer, Demet
dc.date.accessioned2021-11-01T15:05:52Z
dc.date.available2021-11-01T15:05:52Z
dc.date.issued2021
dc.departmentHitit Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü
dc.description.abstractTwo mixed ligand complexes containing acesulfame (acs) and 3-aminopyridine (3-ap) ligands of Mn(II) and Co(II) were synthesized. The obtained compounds were characterized by various analysis methods. The geometries of complexes, C18H28MnN6O12S2 (1) and C18H32CoN6O14S2 (2), are distorted octahedra. Coordination of metal cations is provided by two molecules of 3-ap and four water ligands. In both structures, the 2+ charge of the metal required two monoanionic acs molecules located outside the coordination sphere. Complex 1 contains no hydrate water, while 2 contains two molecules of hydrate water. The crystal system of 1 is monoclinic and space group P2(1)/c, while the crystal system of 2 is triclinic and space group P-1. Data on the removal of hydrate and crystalline waters in structures from thermal analysis curves support the described molecular structures. The bending vibrations of the bonds obtained from the FT-IR spectra match the crystal structure described. As a result of thermal analysis of both complexes, it was determined that the relevant metal cations remained in the reaction vessel as oxide (MnO and CoO) residues.
dc.identifier.citationYurdakul, Ö., Köse, D. A., Şahin, O., & Özer, D. (2021). Mn (II) and Co (II) mixed-ligand coordination compounds with acesulfame and 3-aminopyridine: synthesis and structural properties. Journal of Coordination Chemistry, 74(7), 1168-1180.
dc.identifier.doi10.1080/00958972.2021.1888083
dc.identifier.endpage1180en_US
dc.identifier.issn0095-8972
dc.identifier.issn1029-0389
dc.identifier.issue7en_US
dc.identifier.scopus2-s2.0-85102252527
dc.identifier.scopusqualityQ3
dc.identifier.startpage1168en_US
dc.identifier.urihttps://doi.org/10.1080/00958972.2021.1888083
dc.identifier.urihttps://hdl.handle.net/11491/7426
dc.identifier.volume74en_US
dc.identifier.wosWOS:000626933900001
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorYurdakul, Ömer
dc.institutionauthorKöse, Dursun Ali
dc.language.isoen
dc.publisherTaylor & Francis Ltd
dc.relation.ispartofJournal Of Coordination Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectAcesulfameen_US
dc.subject3-aminopyridineen_US
dc.subjectMetal Complexesen_US
dc.subjectCrystal Structuresen_US
dc.subjectThermal Analysisen_US
dc.titleMn(II) and Co(II) mixed-ligand coordination compounds with acesulfame and 3-aminopyridine: synthesis and structural properties
dc.typeArticle

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