A mononuclear, mixed (salicylato) (nicotinamide) complex of Zn(II) with penta- and hexa-coordination sites: A novel framework structure

Basit Öğe Kaydı
dc.authorid0000-0003-4767-6799
dc.contributor.authorKöse, Dursun Ali
dc.contributor.authorAy, Ahmet Nedim
dc.contributor.authorŞahin, Onur
dc.contributor.authorBüyükgüngör, Orhan
dc.date.accessioned2019-05-13T09:08:49Z
dc.date.available2019-05-13T09:08:49Z
dc.date.issued2012
dc.departmentHitit Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü
dc.description.abstractThe title compound, diaqua(bissalicylato-?O)(bisnicotinamide-?N)zinc(II)][bis(triaqua (monosalicylato-?O)(mononicotinamide-?N)zinc(II)salicylate, includes three Zn(II) ions, four nicotinamide ligands, six salicylate ligands and eight coordinated aqua ligands in the asymmetric unit in complex structure. The geometry around one of the Zn(II) ions is a slightly distorted octahedron, of which the equatorial plane is formed by two carboxylate oxygens and two aqua oxygens, while the axial positions are occupied by two pyridyl nitrogen atoms. The other Zn(II) ions adopt fivefold coordinations with one carboxylate oxygen atom from salicylate ligand, one N atom from nicotinamide ligand and three oxygen atoms from aqua ligands. In addition, there are two salicylate anions in the unit cell that are not coordinated. They provide charge balance as counter-ions in the complex framework.
dc.identifier.citationKöse, D. A., Ay, A. N., Şahin, O., Büyükgüngör, O. (2012). A mononuclear, mixed (salicylato)(nicotinamide) complex of Zn (II) with penta-and hexa-coordination sites: a novel framework structure. Journal of the Iranian Chemical Society, 9(4), 591-597.
dc.identifier.doi10.1007/s13738-012-0072-9
dc.identifier.endpage597en_US
dc.identifier.issn1735-207X
dc.identifier.issue4en_US
dc.identifier.scopusqualityQ2
dc.identifier.startpage591en_US
dc.identifier.urihttps://doi.org/10.1007/s13738-012-0072-9
dc.identifier.urihttps://hdl.handle.net/11491/2057
dc.identifier.volume9en_US
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.relation.ispartofJournal of the Iranian Chemical Society
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectHexa-Coordinated Zn(II)en_US
dc.subjectMixed Ligand Complexesen_US
dc.subjectNicotinamide Complexesen_US
dc.subjectPenta-Coordinated Zn(II)en_US
dc.subjectSalicylic Acid Complexesen_US
dc.subjectZn(II) Complexesen_US
dc.titleA mononuclear, mixed (salicylato) (nicotinamide) complex of Zn(II) with penta- and hexa-coordination sites: A novel framework structure
dc.typeArticle

Dosyalar

Koleksiyon

Scopus İndeksli Yayınlar Koleksiyonu
Makale Koleksiyonu
WoS İndeksli Yayınlar Koleksiyonu