Preparation and spectroscopic studies of Fe(II), Ru(II), Pd(II) and Zn(II) complexes of Schiff base containing terephthalaldehyde and their transfer hydrogenation and Suzuki-Miyaura coupling reaction

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dc.authoridTuran, Nevin / 0000-0001-6740-6812
dc.authoridOzdemir, Ismail / 0000-0001-6325-0216
dc.authorwosidBULDURUN, Kenan / AAD-5162-2019
dc.authorwosidTuran, Nevin / AAB-8583-2019
dc.authorwosidOzdemir, Ismail / ABI-5192-2020
dc.contributor.authorTuran, Nevin
dc.contributor.authorBuldurun, Kenan
dc.contributor.authorColak, Naki
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2021-11-01T15:02:55Z
dc.date.available2021-11-01T15:02:55Z
dc.date.issued2019
dc.department[Belirlenecek]
dc.description.abstractThis study describes synthesis, spectroscopic characterization and catalytic activities of Fe(II), Ru(II), Pd(II) and Zn(II) complexes with a novel Schiff base ligand (L) derived from methyl 2-amino-5,5,7,7-tetramethyl-4,5,6,7-tetrahydrobenzo[b] thiophene-3-carboxylate and terephthalaldehyde. We used spectroscopic techniques including IR, UV-Vis, H-1-NMR, C-13-NMR, elemental analysis and also mass analysis and magnetic susceptibility measurements to identify the products. The Pd(II) complex was used as a potential catalyst for Suzuki-Miyaura coupling reaction of some aryl halides under optimized conditions. The effect of various bases such as NaOH, KOH, and KOBut was investigated in transfer hydrogenation (TH) of ketones by isopropyl alcohol as the hydrogen source. Ru(II) and Pd(II) complexes showed catalytic activity while Zn(II) and Fe(II) metal complexes failed to do that.
dc.description.sponsorshipProjects Research and Practice Center (BAYPUAM) [MSU15-FEF-G01]; Scientific Research-Publicationsen_US
dc.description.sponsorshipThank to Scientific Research-Publications and Projects Research and Practice Center (BAYPUAM) under research project no MSU15-FEF-G01 for their support.en_US
dc.identifier.doi10.1515/chem-2019-0074
dc.identifier.endpage580en_US
dc.identifier.issn2391-5420
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-85073365892
dc.identifier.scopusqualityQ2
dc.identifier.startpage571en_US
dc.identifier.urihttps://doi.org/10.1515/chem-2019-0074
dc.identifier.urihttps://hdl.handle.net/11491/6851
dc.identifier.volume17en_US
dc.identifier.wosWOS:000488211600011
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthor[Belirlenecek]
dc.language.isoen
dc.publisherSciendo
dc.relation.ispartofOpen Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectCatalysisen_US
dc.subjectMetal complexesen_US
dc.subjectThiophene carboxylateen_US
dc.subjectTerephthalaldehydeen_US
dc.subjectSchiff baseen_US
dc.titlePreparation and spectroscopic studies of Fe(II), Ru(II), Pd(II) and Zn(II) complexes of Schiff base containing terephthalaldehyde and their transfer hydrogenation and Suzuki-Miyaura coupling reaction
dc.typeArticle

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