Fabrication and characterization of magnesium and calcium trimesate complexes via ion-exchange and one-pot self-assembly reaction

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dc.authorid0000-0003-4767-6799
dc.contributor.authorÖzer, Demet
dc.contributor.authorAltuntaş Öztaş, Nurşen
dc.contributor.authorKöse, Dursun Ali
dc.contributor.authorŞahin, Onur
dc.date.accessioned2019-05-10T09:38:59Z
dc.date.available2019-05-10T09:38:59Z
dc.date.issued2018
dc.departmentHitit Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü
dc.description.abstractUsing two different synthesis methods, two diversified magnesium and calcium complexes were successfully prepared. When the ion exchange method was used, C9H14MgO11.H2O and C18H30Ca3O24 complexes were obtained. When the one-pot self-assembly reaction was used, C18H34Mg3O26.4H2O and C9H12CaO10 complexes were produced. The structural characterizations were performed by using X-ray diffraction, FT-IR and elemental analyses. Thermal behavior of complexes were also determined via TGA method. The both complexes of magnesium and calcium trimesate have micro and mesoporosity with low porosity because of hydrogen bonds. Then hydrogen storage capacities of complexes were also determined. The differences in synthesis method result in the differences on complexes structure, morphology (shape, particle size and specific surface area) and hydrogen storage capacities. © 2017 Elsevier B.V.
dc.identifier.citationOzer, D., Oztas, N. A., Köse, D. A., & Şahin, O. (2018). Fabrication and characterization of magnesium and calcium trimesate complexes via ion-exchange and one-pot self-assembly reaction. Journal of Molecular Structure, 1156, 353-359.
dc.identifier.doi10.1016/j.molstruc.2017.11.128
dc.identifier.endpage359en_US
dc.identifier.issn0022-2860
dc.identifier.scopusqualityQ1
dc.identifier.startpage353en_US
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2017.11.128
dc.identifier.urihttps://hdl.handle.net/11491/576
dc.identifier.volume1156en_US
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier B.V.
dc.relation.ispartofJournal of Molecular Structure
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectCalcium Trimesateen_US
dc.subjectIon Exchangeen_US
dc.subjectMagnesium Trimesateen_US
dc.subjectMOFen_US
dc.subjectOne-Pot Self-Assembly Reactionen_US
dc.titleFabrication and characterization of magnesium and calcium trimesate complexes via ion-exchange and one-pot self-assembly reaction
dc.typeArticle

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