Synthesis and characterization of boric acid mediated metal-organic frameworks based on trimesic acid and terephthalic acid

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dc.authorid0000-0003-4767-6799
dc.contributor.authorÖzer, Demet
dc.contributor.authorKöse, Dursun Ali
dc.contributor.authorŞahin, Onur
dc.contributor.authorAltuntaş Öztaş, Nurşen
dc.date.accessioned2019-05-10T09:38:59Z
dc.date.available2019-05-10T09:38:59Z
dc.date.issued2017
dc.departmentHitit Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü
dc.description.abstractThe new metal-organic framework materials based on boric acid reported herein. Sodium and boron containing metal-organic frameworks were synthesized by one-pot self-assembly reaction in the presence of trimesic acid and terephthalic acid in water/ethanol solution. Boric acid is a relatively cheap boron source and boric acid mediated metal-organic framework prepared mild conditions compared to the other boron source based metal-organic framework. The synthesized compounds were characterized by FT-IR, p-XRD, TGA/DTA, elemental analysis, 13C-MAS NMR, 11B-NMR and single crystal measurements. The molecular formulas of compounds were estimated as C18H33B2Na5O28 and C8H24B2Na2O17 according to the structural analysis. The obtained complexes were thermally stable. Surface properties of inorganic polymer complexes were investigated by BET analyses and hydrogen storage properties of compound were also calculated. © 2017 Elsevier B.V.
dc.identifier.citationOzer, D., Köse, D. A., Şahin, O., & Oztas, N. A. (2017). Synthesis and characterization of boric acid mediated metal-organic frameworks based on trimesic acid and terephthalic acid. Journal of Molecular Structure, 1141, 261-267.
dc.identifier.doi10.1016/j.molstruc.2017.03.120
dc.identifier.endpage267en_US
dc.identifier.issn0022-2860
dc.identifier.scopusqualityQ1
dc.identifier.startpage261en_US
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2017.03.120
dc.identifier.urihttps://hdl.handle.net/11491/578
dc.identifier.volume1141en_US
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier B.V.
dc.relation.ispartofJournal of Molecular Structure
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectB-MOFen_US
dc.subjectBoric Aciden_US
dc.subjectSodiumen_US
dc.subjectTerephthalic Aciden_US
dc.subjectTrimesic Aciden_US
dc.titleSynthesis and characterization of boric acid mediated metal-organic frameworks based on trimesic acid and terephthalic acid
dc.typeArticle

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