Synthetic routes to manganese oxoborate and correlations between experimental parameters and properties

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dc.authoridÖzgenç, Gökhan / 0000-0001-7188-4112
dc.authoridErtekin, Zeliha / 0000-0001-6106-7987
dc.authoridÖzer, Demet / 0000-0003-0862-9607
dc.contributor.authorİçten, Orkun
dc.contributor.authorÖzgenç, Gökhan
dc.contributor.authorÖzer, Demet
dc.contributor.authorKöse, Dursun Ali
dc.contributor.authorElmacı, Gökhan
dc.contributor.authorErtekin, Zeliha
dc.contributor.authorZümreoğlu Karan, Birgül
dc.date.accessioned2021-11-01T15:05:48Z
dc.date.available2021-11-01T15:05:48Z
dc.date.issued2021
dc.departmentHitit Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü
dc.description.abstractThis study examines manganese oxoborate synthesis in three different routes and the role of process parameters on structure and morphology of the products. Borax or boric acid and simple manganese salts were used as raw materials. In this regard, the samples prepared by hydrothermal, solid-state, and solution combustion methods were characterized by powder X-ray diffraction (XRD), vibrational spectroscopy (FT-IR and Raman), thermal analysis (DSC and TGA), scanning and transmission electron microscopy (SEM and TEM), chemical analysis and BET surface area measurements. It was found that all three strategies yielded warwickite-type Mn2OBO3 nanoparticles, but with significant changes in morphology, size, and surface characteristics. The hydrothermal approach has proven to be a general approach for synthesizing manganese oxoborate nanorods at pH 7.5. Solution combustion technique appeared the most practical and promising not only as a time-saving route but also in the production of ca. 100 nm, quasi-spherical, mesoporous manganese oxoborate nanoparticles.
dc.description.sponsorshipTENMAK-National Boron Research Institute, Turkey [2018-30-06-30-005]en_US
dc.description.sponsorshipWe gratefully acknowledge the financial and technical support provided by TENMAK-National Boron Research Institute, Turkey (grant number: 2018-30-06-30-005).en_US
dc.identifier.citationIcten, O., Ozgenc, G., Ozer, D., Kose, D. A., Elmaci, G., Ertekin, Z., ... & Zumreoglu-Karan, B. (2021). Synthetic routes to manganese oxoborate and correlations between experimental parameters and properties. Ceramics International, 47(12), 17353-17360.
dc.identifier.doi10.1016/j.ceramint.2021.03.049
dc.identifier.endpage17360en_US
dc.identifier.issn0272-8842
dc.identifier.issn1873-3956
dc.identifier.issue12en_US
dc.identifier.scopus2-s2.0-85102455292
dc.identifier.scopusqualityQ1
dc.identifier.startpage17353en_US
dc.identifier.urihttps://doi.org/10.1016/j.ceramint.2021.03.049
dc.identifier.urihttps://hdl.handle.net/11491/7406
dc.identifier.volume47en_US
dc.identifier.wosWOS:000648613400007
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorKöse, Dursun Ali
dc.language.isoen
dc.publisherElsevier Sci Ltd
dc.relation.ispartofCeramics International
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectManganese Oxoborateen_US
dc.subjectWarwickiteen_US
dc.subjectHydrothermal Synthesisen_US
dc.subjectSolid-state Synthesisen_US
dc.subjectSolution Combustion Synthesisen_US
dc.titleSynthetic routes to manganese oxoborate and correlations between experimental parameters and properties
dc.typeArticle

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