Synthesis, spectroscopic studies and electrochemical properties of Schiff bases derived from 5-chloro-2-hydroxybenzaldehyde with methyl 2-amino-6-methyl-4,5,6,7-tetrahydrobenzo[b] thiophene-3-carboxylate
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Tarih
2016
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Bulgarian Acad Science
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Schiff base; methyl 2-((5-chloro-2-hydroxybenzylidene) amino)-6-methyl-4,5,6,7-tetrahydrothieno[ 2,3-c] pyridine-3-carboxylate was synthesized by the reaction of methyl 2-amino-6-methyl-4,5,6,7-tetrahydrothieno[2,3-c] pyridine-3-carboxylate with 5-chloro-2-hydroxybenzaldehyde in excellent yield. This compound was characterized by elemental analysis, NMR (H-1 and C-13-APT), FT-IR and X-ray diffraction methods. The electrochemical behavior of Schiff base was investigated using cyclic voltammetry (CV), controlled potential electrolysis and chronoamperometry (CA) techniques. The number of electrons transferred (n), diffusion coefficient (D) and standard heterogeneous rate constants (k(s)) were also determined by electrochemical methods.
Açıklama
Anahtar Kelimeler
Schiff base, 2-aminothiophene, X-ray diffraction, electrochemical behavior
Kaynak
Bulgarian Chemical Communications
WoS Q Değeri
N/A
Scopus Q Değeri
Cilt
48
