Boric acid complexes with organic biomolecules: Mono-chelate complexes with salicylic and glucuronic acids

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dc.authorid0000-0003-4767-6799
dc.contributor.authorKöse, Dursun Ali
dc.contributor.authorZümreoğlu Karan, Birgül
dc.contributor.authorHökelek, Tuncer
dc.contributor.authorŞahin, Ertan
dc.date.accessioned2019-05-10T09:38:53Z
dc.date.available2019-05-10T09:38:53Z
dc.date.issued2010
dc.departmentHitit Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü
dc.description.abstractTwo mono-chelate borate complexes, lithium mono-salicylatoborate and sodium mono-glucuronatoborate, are reported for the first time. The complexes were isolated from aqueous solutions and characterized by FTIR (Fourier Transform Infrared) and 13C MAS (Magic Angle Spinning) NMR techniques. Thermal stabilities of the complexes were examined by recording their TGA (Thermogravimetric Analysis) curves. Lithium mono-salicylatoborate, Li[B(Sal)(OH)2], was isolated in crystal form and presented as a novel hybrid metal-organic framework possessing zeolitic structure. X-ray analysis revealed an original crystal structure constructed with solvate-free lithium ions adopting two different types of coordination polyhedra, corner-sharing LiO4 (tetrahedral) and LiO5 (distorted square pyramidal), in the same framework. © 2010 Elsevier B.V. All rights reserved.
dc.identifier.citationKöse, D. A., Zümreoglu-Karan, B., Hökelek, T., Şahin, E. (2010). Boric acid complexes with organic biomolecules: Mono-chelate complexes with salicylic and glucuronic acids. Inorganica Chimica Acta, 363(14), 4031-4037.
dc.identifier.doi10.1016/j.ica.2010.08.001
dc.identifier.endpage4037en_US
dc.identifier.issn0020-1693
dc.identifier.issue14en_US
dc.identifier.scopusqualityQ2
dc.identifier.startpage4031en_US
dc.identifier.urihttps://doi.org/10.1016/j.ica.2010.08.001
dc.identifier.urihttps://hdl.handle.net/11491/535
dc.identifier.volume363en_US
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.relation.ispartofInorganica Chimica Acta
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subject13C MAS NMRen_US
dc.subjectBorate Esteren_US
dc.subjectBoric Aciden_US
dc.subjectCrystal Structureen_US
dc.subjectGlucuronic Aciden_US
dc.subjectSalicylic Aciden_US
dc.titleBoric acid complexes with organic biomolecules: Mono-chelate complexes with salicylic and glucuronic acids
dc.typeArticle

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