ZrO2 coating via e-beam evaporation on PE separators for lithium-ion batteries

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Tarih

2021

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Springer Heidelberg

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

In this paper, ZrO2 is deposited on a polyethylene-based separator via electron beam evaporation method. The analyses reveal that the application of the ceramic-based coating enhances the electrolyte uptake capability from 79 to 135% and the ionic conductivity from 7.1 x 10(-4) to 7.5 x 10(-4) S/cm. Linear sweep voltammetry tests show the superior electrochemical stability in the coated separator up to 5.5 V. This study shows that with the thin ZrO2 coating, the separator maintains its structure plus the existence of ZrO2 has an essential impact on electrolyte decomposition, SEI layer formation, and safety of the separator.

Açıklama

Anahtar Kelimeler

E-beam evaporation, Lithium-ion battery, Separator, ZrO2 coating

Kaynak

Ionics

WoS Q Değeri

Q3

Scopus Q Değeri

Q1

Cilt

27

Sayı

2

Künye

Sivlin, D., Unal, F., Karahan, B. D., Kazmanli, K., & Keles, O. (2021). ZrO2 coating via e-beam evaporation on PE separators for lithium-ion batteries. Ionics, 27(2), 577-586.