Magnetic properties of FeMnyCoyFe2?2yO4@Oleylamine nanocomposite with cation distribution

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dc.contributor.authorAmir, Md.
dc.contributor.authorDemir Korkmaz, Ayşe
dc.contributor.authorBaykal, Abdulhadi
dc.contributor.authorGeleri, M.
dc.contributor.authorSözeri, Hüseyin
dc.contributor.authorGüngüneş, Hakan
dc.contributor.authorSertkol, Murat
dc.contributor.authorShirsath, Sagar E.
dc.date.accessioned2019-05-13T09:06:48Z
dc.date.available2019-05-13T09:06:48Z
dc.date.issued2017
dc.departmentHitit Üniversitesi, Fen Edebiyat Fakültesi, Fizik Bölümü
dc.description.abstractIn this study, oleylamine (OAm) capped FeMnyCoyFe2?2yO4 (0.0???y???0.4) nanocomposites (NCs) were prepared via the polyol route and the impact of bimetallic Co3+ and Mn3+ ions on the structural and magnetic properties of Fe3O4 was investigated. The complete characterization of FeMnyCoyFe2?2yO4@OAm NCs were done by different techniques such as XRD, SEM, TGA, FT-IR, TEM, and VSM. XRD analyses proved the successful formation of mono-phase MnFe2O4 spinel cubic products free from any impurity. The average crystallite sizes were calculated in the range of 9.4–26.4 nm using Sherrer’s formula. Both SEM and TEM results confirmed that products are nanoparticles like structures having spherical morphology with small agglomeration. Ms continued to decrease up to Co3+ and Mn3+ content of y?=?0.4. Although Mössbauer analysis reveals that the nanocomposites consist three magnetic sextets and superparamagnetic particles are also formed for Fe3O4, Co0.2Mn0.2Fe2.6O4 and Co0.4Mn0.4Fe2.2O4. Cation distributions calculation was reported that Co3+ ions prefer to replace Fe2+ ions on tetrahedral side up to all the concentration while Mn3+ ions prefer to replace Fe3+ ions on the octahedral.
dc.identifier.citationAmir, M., Korkmaz, A. D., Baykal, A., Geleri, M., Sözeri, H., Güngüneş, H., Shirsath, S. E. (2017). Magnetic properties of FeMn y Co y Fe 2? 2y O 4@ Oleylamine nanocomposite with cation distribution. Journal of Inorganic and Organometallic Polymers and Materials, 27(6), 1740-1749.
dc.identifier.doi10.1007/s10904-017-0637-2
dc.identifier.endpage1749en_US
dc.identifier.issn1574-1443
dc.identifier.issue6en_US
dc.identifier.scopusqualityQ1
dc.identifier.startpage1740en_US
dc.identifier.urihttps://doi.org/10.1007/s10904-017-0637-2
dc.identifier.urihttps://hdl.handle.net/11491/1656
dc.identifier.volume27en_US
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer New York LLC
dc.relation.ispartofJournal of Inorganic and Organometallic Polymers and Materials
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectCation Distributionen_US
dc.subjectFe3O4en_US
dc.subjectMagnetic Nanomaterialsen_US
dc.subjectMagnetic Propertiesen_US
dc.subjectMössbauer Analysisen_US
dc.subjectOleylamineen_US
dc.titleMagnetic properties of FeMnyCoyFe2?2yO4@Oleylamine nanocomposite with cation distribution
dc.typeArticle

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