Synthetic strategies towards the carbenoid reactions of ?, ?-acetylenic carbonyls
Yükleniyor...
Dosyalar
Tarih
2018
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
TÜBİTAK
Erişim Hakkı
Attribution 4.0 International (CC BY 4.0)
info:eu-repo/semantics/openAccess
info:eu-repo/semantics/openAccess
Özet
Catalytic reactions of ?, ?-conjugated carbonyl compounds have been a practical tool towards the synthesis of different useful heterocyclic compounds. Despite the numerous reactions with carbon-carbon double bond conjugated carbonyls, reactions of acetylenic carbonyls are limited. In this study, efficient dioxole synthesis was carried out via acetylenic aldehydes and butadiene formation was preferred over cyclopropene formation via acetylenic esters as different functional groups on these substrates change the product distribution. Both reaction conditions (such as solvent and temperature) and electrophilic structure of metal carbenoids alter the product distribution; acceptor (A), donor-acceptor (DA), and acceptor-acceptor (AA) functionalized diazo compounds yield different product types over different mechanisms. © 2018 TÜBITAK.
Açıklama
Anahtar Kelimeler
Acetylenic Carbonyl, Butadiene, Carbenoid, Cu(acac)2, Cyclopropene, Diazo, Rh2(OAc)4
Kaynak
Turkish Journal of Chemistry
WoS Q Değeri
N/A
Scopus Q Değeri
Q3
Cilt
42
Sayı
5
Künye
Kışkan, F. S., Özgüz, E., Anaç, O., Tarakçı, N., Merey, G. (2018). Synthetic strategies towards the carbenoid reactions of ?, ?-acetylenic carbonyls. Turkish Journal of Chemistry, 42(5), 1384-1397.
