Synthetic strategies towards the carbenoid reactions of ?, ?-acetylenic carbonyls

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dc.authorid0000-0003-0759-1299
dc.contributor.authorKışkan, Füsun Şeyma
dc.contributor.authorÖzgüz, Emre
dc.contributor.authorAnaç, Olcay
dc.contributor.authorTarakçı, Nurdan
dc.contributor.authorMerey, Gökçe
dc.date.accessioned2019-05-13T09:02:49Z
dc.date.available2019-05-13T09:02:49Z
dc.date.issued2018
dc.departmentHitit Üniversitesi, Mühendislik Fakültesi, Kimya Mühendisliği Bölümü
dc.description.abstractCatalytic reactions of ?, ?-conjugated carbonyl compounds have been a practical tool towards the synthesis of different useful heterocyclic compounds. Despite the numerous reactions with carbon-carbon double bond conjugated carbonyls, reactions of acetylenic carbonyls are limited. In this study, efficient dioxole synthesis was carried out via acetylenic aldehydes and butadiene formation was preferred over cyclopropene formation via acetylenic esters as different functional groups on these substrates change the product distribution. Both reaction conditions (such as solvent and temperature) and electrophilic structure of metal carbenoids alter the product distribution; acceptor (A), donor-acceptor (DA), and acceptor-acceptor (AA) functionalized diazo compounds yield different product types over different mechanisms. © 2018 TÜBITAK.
dc.identifier.citationKışkan, F. S., Özgüz, E., Anaç, O., Tarakçı, N., Merey, G. (2018). Synthetic strategies towards the carbenoid reactions of ?, ?-acetylenic carbonyls. Turkish Journal of Chemistry, 42(5), 1384-1397.
dc.identifier.doi10.3906/kim-1805-65
dc.identifier.endpage1397en_US
dc.identifier.issn1300-0527
dc.identifier.issue5en_US
dc.identifier.scopusqualityQ3
dc.identifier.startpage1384en_US
dc.identifier.urihttps://doi.org/10.3906/kim-1805-65
dc.identifier.urihttps://hdl.handle.net/11491/1340
dc.identifier.volume42en_US
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTÜBİTAK
dc.relation.ispartofTurkish Journal of Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsAttribution 4.0 International (CC BY 4.0)*
dc.rightsinfo:eu-repo/semantics/openAccess
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/*
dc.subjectAcetylenic Carbonylen_US
dc.subjectButadieneen_US
dc.subjectCarbenoiden_US
dc.subjectCu(acac)2en_US
dc.subjectCyclopropeneen_US
dc.subjectDiazoen_US
dc.subjectRh2(OAc)4en_US
dc.titleSynthetic strategies towards the carbenoid reactions of ?, ?-acetylenic carbonyls
dc.typeArticle

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