Hydrogen storage properties of mono-and bidentate MOF structured orotate complexes
[ X ]
Tarih
2014
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Materials Research Society
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
One of the barriers for wide usage of hydrogen energy system is efficient storage. To store more hydrogen efficiently, physisorption is a choice among the others with high storage performance, reversibility, and lifecycles. Metal organic framework (MOF) structured organometallic orotate-Co(II) complexes could serve as sorbents which store hydrogen by physisorption. In this work, mono-and bidentate MOF structured orotate-Co(II) complexes are synthesized, characterized, and then investigated for hydrogen storage experimentally and theoretically. It is found that these compounds could store hydrogen. Especially, the monodentate complex could uptake hydrogen better than the other. Storage performances for mono-and bidentate complexes were 0.80 and 1.15 wt% at 77 K and approximately 80 bars experimentally, 1.03 and 1.16 wt% theoretically for the same conditions. © 2013 Materials Research Society.
Açıklama
Anahtar Kelimeler
Hydrogen Storage, MOFs, Mono-and Bidentate, Orotate Complex
Kaynak
Journal of Materials Research
WoS Q Değeri
N/A
Scopus Q Değeri
Q2
Cilt
29
Sayı
2
Künye
Öztürk, Z., Köse, D. A., Asan, A., Öztürk, B., Andaç, O., Özkan, G. (2014). Hydrogen storage properties of mono-and bidentate MOF structured orotate complexes. Journal of Materials Research, 29(2), 215-220.
