Hydrogen storage properties of mono-and bidentate MOF structured orotate complexes

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dc.authorid0000-0003-4767-6799
dc.contributor.authorÖztürk, Zeynel
dc.contributor.authorKöse, Dursun Ali
dc.contributor.authorAsan, Abdurrahman
dc.contributor.authorÖztürk, Banu
dc.contributor.authorAndaç, Ömer
dc.contributor.authorÖzkan, Göksel
dc.date.accessioned2019-05-13T08:57:51Z
dc.date.available2019-05-13T08:57:51Z
dc.date.issued2014
dc.departmentHitit Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü
dc.description.abstractOne of the barriers for wide usage of hydrogen energy system is efficient storage. To store more hydrogen efficiently, physisorption is a choice among the others with high storage performance, reversibility, and lifecycles. Metal organic framework (MOF) structured organometallic orotate-Co(II) complexes could serve as sorbents which store hydrogen by physisorption. In this work, mono-and bidentate MOF structured orotate-Co(II) complexes are synthesized, characterized, and then investigated for hydrogen storage experimentally and theoretically. It is found that these compounds could store hydrogen. Especially, the monodentate complex could uptake hydrogen better than the other. Storage performances for mono-and bidentate complexes were 0.80 and 1.15 wt% at 77 K and approximately 80 bars experimentally, 1.03 and 1.16 wt% theoretically for the same conditions. © 2013 Materials Research Society.
dc.identifier.citationÖztürk, Z., Köse, D. A., Asan, A., Öztürk, B., Andaç, O., Özkan, G. (2014). Hydrogen storage properties of mono-and bidentate MOF structured orotate complexes. Journal of Materials Research, 29(2), 215-220.
dc.identifier.doi10.1557/jmr.2013.357
dc.identifier.endpage220en_US
dc.identifier.issn0884-2914
dc.identifier.issue2en_US
dc.identifier.scopusqualityQ2
dc.identifier.startpage215en_US
dc.identifier.urihttps://doi.org/10.1557/jmr.2013.357
dc.identifier.urihttps://hdl.handle.net/11491/1021
dc.identifier.volume29en_US
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherMaterials Research Society
dc.relation.ispartofJournal of Materials Research
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectHydrogen Storageen_US
dc.subjectMOFsen_US
dc.subjectMono-and Bidentateen_US
dc.subjectOrotate Complexen_US
dc.titleHydrogen storage properties of mono-and bidentate MOF structured orotate complexes
dc.typeArticle

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