A novel fluorinated monomer: Synthesis, characterization and ATRP of 5,6,7,8-tetrafluoronaphthalen-1-yl acrylate

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dc.authoridBALABAN, Humeyra MERT / 0000-0002-8036-8678
dc.authoridERDOGAN, Musa / 0000-0001-6097-2862
dc.authorwosidBALABAN, Humeyra MERT / AAE-4061-2019
dc.contributor.authorErdoğan, Musa
dc.contributor.authorÖzkınalı, Sevil
dc.contributor.authorMert Balaban, Hümeyra
dc.date.accessioned2021-11-01T15:05:32Z
dc.date.available2021-11-01T15:05:32Z
dc.date.issued2021
dc.department[Belirlenecek]
dc.description.abstractA new fluorinated naphthyl-acrylate based monomer was synthesized in three steps, namely the addition reaction of furan via Diels Alder cycloaddition reaction, acid catalyzed aromatization reaction and Schotten-Baumann esterification reaction, respectively. The structure of the precursors and the target compound was characterized comprehensively by FT-IR, UV-vis, H-1 NMR, C-13 NMR, F-19 NMR and LC-MS/MS measurements. Atom transfer radical polymerization (ATRP) was used for the polymerization of 5,6,7,8-tetrafluomnaphthalen-1-yl acrylate. The successful polymerization of this novel monomer was verified by FT-IR and GPC analyses. Particularly, DSC and TGA analyses showed that the poly(5,6,7,8-tetrafluoronaphthalen-1-yl acrylate) has a glass transition temperature of 105-110 degrees C and starts to degrade after 150 degrees C. The results showed that the proposed monomer can be synthesized in yields overpassing 80 % by using the aforementioned reaction sequence. Our results revealed that 5,6,7,8-tetrafluom naphthalen-1-yl acrylate could be acceptable as a promising monomer candidate in the field of synthetic polymer chemistry.
dc.identifier.doi10.1016/j.jfluchem.2020.109718
dc.identifier.issn0022-1139
dc.identifier.issn1873-3328
dc.identifier.scopus2-s2.0-85098542994
dc.identifier.scopusqualityQ2
dc.identifier.urihttps://doi.org/10.1016/j.jfluchem.2020.109718
dc.identifier.urihttps://hdl.handle.net/11491/7314
dc.identifier.volume242en_US
dc.identifier.wosWOS:000609574500014
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorÖzkınalı, Sevil
dc.institutionauthorMert Balaban, Hümeyra
dc.language.isoen
dc.publisherElsevier Science Sa
dc.relation.ispartofJournal Of Fluorine Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectTetrafluoronaphtholen_US
dc.subjectFluorinated aromatic monomeren_US
dc.subjectAcrylateen_US
dc.subjectATRPen_US
dc.subjectF-19 NMRen_US
dc.titleA novel fluorinated monomer: Synthesis, characterization and ATRP of 5,6,7,8-tetrafluoronaphthalen-1-yl acrylate
dc.typeArticle

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