Novel coordination compounds: Mn(II), Co(II), Ni(II), Cu(II), and Zn(II) cations with acesulfame/N,N-diethylnicotinamide ligands

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dc.authorid0000-0003-4767-6799
dc.authorid0000-0003-4049-0756
dc.contributor.authorYıldırım, Tuğrul
dc.contributor.authorKöse, Dursun Ali
dc.contributor.authorAlp Avcı, Gülçin
dc.contributor.authorŞahin, Onur
dc.contributor.authorAkkurt, Fatih
dc.date.accessioned2020-02-10T11:29:42Z
dc.date.available2020-02-10T11:29:42Z
dc.date.issued2020en_US
dc.departmentHitit Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü
dc.description.abstractFive coordination complexes with Mn2? (1), Co2? (2), Ni2? (3), Cu2? (4), and Zn2? (5) containing acesulfame (ace) and N,N-diethylnicotinamide (dena) ligands were synthesized and structural binding properties investigated. Four compounds (1, 2, 4, and 5) were examined with single crystal X-ray diffraction methods. The structures containing Mn(II), Co(II), and Zn(II) were iso-structural. Six-coordination of metal cations were completed with two moles dena and four aqua ligands. The dena ligands were coordinated via pyridine nitrogen as neutral-monodentate. Charge stabilities of the complexes are complemented by two moles monoanionic ace ligands, located outside of the coordination unit. In the Cu(II) complex, the coordination is completed by acidic nitrogen and carbonyl oxygen atoms of two ace ligands and pyridine nitrogen of two moles dena ligands. The coordination to Cu(II) for ace ligands was monoanionic-bidentate. All metal cations in the structure are distorted octahedral. Thermal decomposition of complexes begins with removal of the aqua molecules from the structures and is completed by combustion of organic ligands. The final decomposition products of all structures have been identified as corresponding metal oxides. Some biological applications (anti-fungal/anti-bacterial) were studied using 1–5.
dc.description.provenanceSubmitted by Zeynep Umut Arslan (umutarslan@hitit.edu.tr) on 2020-02-10T11:29:21Z No. of bitstreams: 0en
dc.description.provenanceApproved for entry into archive by Zeynep Umut Arslan (umutarslan@hitit.edu.tr) on 2020-02-10T11:29:42Z (GMT) No. of bitstreams: 0en
dc.description.provenanceMade available in DSpace on 2020-02-10T11:29:42Z (GMT). No. of bitstreams: 0 Previous issue date: 2020en
dc.identifier.citationYildirim, T., Köse, D. A., Avci, G. A., Şahin, O., Akkurt, F. (2020). Novel coordination compounds: Mn (II), Co (II), Ni (II), Cu (II), and Zn (II) cations with acesulfame/N, N-diethylnicotinamide ligands. Journal of Coordination Chemistry, 72, 3502-3517.
dc.identifier.doi10.1080/00958972.2019.1705970
dc.identifier.endpage3517en_US
dc.identifier.issn0095-8972
dc.identifier.issn1029-0389
dc.identifier.scopusqualityQ3
dc.identifier.startpage3502en_US
dc.identifier.urihttps://doi.org/10.1080/00958972.2019.1705970
dc.identifier.urihttps://hdl.handle.net/11491/5726
dc.identifier.volume72en_US
dc.identifier.wosWOS:000508330200001
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTaylor and Francis Ltd.
dc.relation.ispartofJournal of Coordination Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectAcesulfameen_US
dc.subjectN,N-diethylnicotinamideen_US
dc.subjectCoordination Compoundsen_US
dc.subjectAntimicrobial Studiesen_US
dc.subjectStructural Propertiesen_US
dc.subjectThermal Investigationen_US
dc.titleNovel coordination compounds: Mn(II), Co(II), Ni(II), Cu(II), and Zn(II) cations with acesulfame/N,N-diethylnicotinamide ligands
dc.typeArticle

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