Synthesis, spectral, and thermal studies of Co(II), Ni(II), Cu(II), and Zn(II)-glycinato complexes and ınvestigation of their biological properties: Crystal structure of [Cu(µ-gly)2(H2O)]n

[ X ]

Tarih

2016

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Taylor and Francis Inc.

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

The complexes of metal cations with glycine amino acid were synthesized and characterized by FTIR, TGA, UV-Vis, and elemental analysis methods. Just the CuII-complex was suitably obtained as a single crystal. Neighboring chains are linked together to form a three-dimensional network via hydrogen-bonding interactions between coordinated water molecule, amino atoms, and O atoms of the bridging carboxylate groups. The other complex structures were thought to be similar to the CuII structure, and because of their spectroscopic studies they are similar to each other. Finally, the biological activities of complexes were investigated. The metal complexes showed more antimicrobial activity. The total antioxidant capacity of the metal complexes was determined. © 2016 Taylor and Francis Group, LLC.

Açıklama

Anahtar Kelimeler

Antimicrobial And Antioxidant, Helix Crystal Structure, Metal Complexes, Polymeric Glycinate, Thermal Decomposition

Kaynak

Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry

WoS Q Değeri

N/A

Scopus Q Değeri

N/A

Cilt

46

Sayı

7

Künye

Köse, D. A., Toprak, E., Kaşarcı, A., Avcı, E., Avcı, G. A., Şahin, O., Büyükgüngör, O. (2016). SSynthesis, spectral, and thermal studies of Co(II), Ni(II), Cu(II), and Zn(II)-glycinato complexes and ınvestigation of their biological properties: Crystal structure of [Cu(µ-gly)2(H2O)]n. Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 46(7), 1109-1118.