Synthesis, characterization, antioxidant, antimicrobial and DNA binding properties of ruthenium(II), cobalt(II) and nickel(II) complexes of Schiff base containing o-vanillin

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dc.authorid0000-0001-7181-9556
dc.contributor.authorTuran, Nevin
dc.contributor.authorBuldurun, Kenan
dc.contributor.authorAlan, Yusuf
dc.contributor.authorSavcı, Ahmet
dc.contributor.authorÇolak, Naki
dc.contributor.authorMantarcı, Asım
dc.date.accessioned2019-05-13T08:58:02Z
dc.date.available2019-05-13T08:58:02Z
dc.date.issued2019
dc.departmentHitit Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü
dc.description.abstractIn this study, the complex combinations of Ru(II), Co(II) and Ni(II) with Schiff base obtained through the condensation of (E)-methyl 2-amino-6-methyl-4,5,6,7-tetrahydrothieno[2,3-c]pyridine-3-carboxylate with 2-hydroxy-3-methoxybenzaldehyde (o-vanillin) were prepared. The characterization of newly developed complexes was implemented by IR, elemental analyses, magnetic susceptibility, mass spectra, UV–Vis and thermogravimetry/differential thermal analysis. The X-ray powder diffraction pattern of the complexes was also investigated. The geometries of the complexes were found to be octahedral. Furthermore, antioxidant, antimicrobial and pBR322 plasmid DNA cleavage activities were investigated. The antibacterial effects of the Co(II) complex on Gram-positive and Gram-negative bacteria were identified to be higher than those of ligand. The Ru(II) complex was found to have higher radical scavenging potential on 1,1-diphenyl-2-picryl-hydrazyl (DPPH·), superoxide anion (O 2 ? ), hydroxyl (OH) and 2,2?-azino-bis-3-ethylbenzothiazoline-6-sulfonic acid (ABTS) radicals, in comparison with ligand. The binding affinity of the Ni(II) complex was higher than that of ligand. © 2019, Springer Nature B.V.
dc.identifier.citationTuran, N., Buldurun, K., Alan, Y., Savcı, A., Çolak, N., Mantarcı, A. (2019). Synthesis, characterization, antioxidant, antimicrobial and DNA binding properties of ruthenium (II), cobalt (II) and nickel (II) complexes of Schiff base containing o-vanillin. Research on Chemical Intermediates, 45(6), 3525-3540.
dc.identifier.doi10.1007/s11164-019-03806-3
dc.identifier.issn0922-6168
dc.identifier.scopusqualityQ2
dc.identifier.urihttps://doi.org/10.1007/s11164-019-03806-3
dc.identifier.urihttps://hdl.handle.net/11491/1059
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer Netherlands
dc.relation.ispartofResearch on Chemical Intermediates
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectAntimicrobialen_US
dc.subjectAntioxidanten_US
dc.subjectMetal Complexesen_US
dc.subjectSchiff Baseen_US
dc.subjectX-Ray Powder Diffractionen_US
dc.titleSynthesis, characterization, antioxidant, antimicrobial and DNA binding properties of ruthenium(II), cobalt(II) and nickel(II) complexes of Schiff base containing o-vanillin
dc.typeArticle

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