Novel mixed ligand coordination compounds of some rare earth metal cations containing acesulfamato/N,N-diethylnicotinamide

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dc.contributor.authorZeybel, Leriman
dc.contributor.authorKöse, Dursun Ali
dc.date.accessioned2021-11-01T15:05:25Z
dc.date.available2021-11-01T15:05:25Z
dc.date.issued2021
dc.departmentHitit Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü
dc.departmentHitit Üniversitesi, Rektörlük
dc.description.abstractThe mixed ligand coordination compounds containing acesulfamato and N,N-diethylnicotinamide biomolecules of some rare earth metal cations (Eu3+, Tb3+, Ho3+, Er3+ and Yb3+) were synthesized, and their structural properties were investigated. Possible structural formulas have been proposed by determining the chemical composition of molecules (elemental analysis), binding properties (infrared spectroscopy, mass analysis, solid-state UV-vis spectroscopy), thermal degradation properties (TGA / DTA curves). Based on the data collected, it is suggested that rare earth metal cations with a 3+ oxidation state have sextet coordination. The geometries of the structures were thought to be distorted octahedral. The charge balance of the coordination sphere is balanced by a monoanionic acesulfamato located outside the coordination sphere. When the thermal behaviours of the complexes were examined, it was determined that the compounds with Eu3+, Tb3+, and Yb3+ metal cations contained one hydrate water outside the coordination sphere. Hydrate waters do not exist in the Ho3+ and Er3+ metal cation-centred complexes. At the end of the thermal decomposition analysis of all complex structures, it was determined that they leave the relevant metal oxides in the reaction vessels as final decomposition products.
dc.description.sponsorshipHitit University Unit of Scientific Research Projects [FEF19004.16.004]en_US
dc.description.sponsorshipThe authors acknowledge the Hitit University Unit of Scientific Research Projects (FEF19004.16.004).en_US
dc.identifier.citationZeybel, L., & Köse, D. A. (2021). Novel mixed ligand coordination compounds of some rare earth metal cations containing acesulfamato/N, N-diethylnicotinamide. Turkish Journal of Chemistry, 45(4), 1004-1115.
dc.identifier.doi10.3906/kim-2012-47
dc.identifier.endpage1015en_US
dc.identifier.issn1300-0527
dc.identifier.issue4en_US
dc.identifier.pmid34707430
dc.identifier.scopus2-s2.0-85113972642
dc.identifier.scopusqualityQ3
dc.identifier.startpage1004en_US
dc.identifier.urihttps://doi.org/10.3906/kim-2012-47
dc.identifier.urihttps://hdl.handle.net/11491/7268
dc.identifier.volume45en_US
dc.identifier.wosWOS:000691324800001
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.institutionauthorZeybel, Leriman
dc.institutionauthorKöse, Dursun Ali
dc.language.isoen
dc.publisherScientific Technical Research Council Turkey-Tubitak
dc.relation.ispartofTurkish Journal Of Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectRare-earth Metal Complexesen_US
dc.subjectAcesulfamatoen_US
dc.subjectN,N-diethylnicotinamideen_US
dc.subjectStructural Characterizationen_US
dc.subjectThermal Analysisen_US
dc.subjectMixed Ligand Complexesen_US
dc.titleNovel mixed ligand coordination compounds of some rare earth metal cations containing acesulfamato/N,N-diethylnicotinamide
dc.typeArticle

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